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Polycarbonate is commonly used in eye protection, as well as in other projectile-resistant viewing and lighting applications that would normally indicate the use of glass, but require much higher impact-resistance. Polycarbonate lenses also protect the eye from UV light.
A polycarbonate is an oxocarbon dianion consisting of a chain of carbonate units, where successive carbonyl groups are directly linked to each other by shared additional oxygen atoms. That is, they are the conjugate bases of polycarbonic acids , the conceptual anhydrides of carbonic acid , or polymers of carbon dioxide .
The Flory–Fox equation relates the number-average molecular weight, M n, to the glass transition temperature, T g, as shown below: =, where T g,∞ is the maximum glass transition temperature that can be achieved at a theoretical infinite molecular weight and K is an empirical parameter that is related to the free volume present in the polymer sample.
In this equation, k is the number of monomers in the chain, [1] and 0<a<1 is an empirically determined constant related to the fraction of unreacted monomer remaining. [ 2 ] The form of this distribution implies is that shorter polymers are favored over longer ones -the chain length is geometrically distributed .
The calculation of glass properties allows "fine-tuning" of desired material characteristics, e.g., the refractive index. [1]The calculation of glass properties (glass modeling) is used to predict glass properties of interest or glass behavior under certain conditions (e.g., during production) without experimental investigation, based on past data and experience, with the intention to save ...
The Sellmeier equation is an empirical relationship between refractive index and wavelength for a particular transparent medium. The equation is used to determine the dispersion of light in the medium. It was first proposed in 1872 by Wolfgang Sellmeier and was a development of the work of Augustin Cauchy on Cauchy's equation for modelling ...
Values of range from below 25 for very dense flint glasses, around 34 for polycarbonate plastics, up to 65 for common crown glasses, and 75 to 85 for some fluorite and phosphate crown glasses. Most of the human eye's wavelength sensitivity curve, shown here, is bracketed by the Abbe number reference wavelengths of 486.1 nm (blue) and 656.3 nm (red)
From this equation the molecular weight of a polymer can be determined from data on the intrinsic viscosity and vice versa. The values of the Mark–Houwink parameters, and , depend on the particular polymer-solvent system. For solvents, a value of = is indicative of a theta solvent.