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Pulsed electron paramagnetic resonance (EPR) is an electron paramagnetic resonance technique that involves the alignment of the net magnetization vector of the electron spins in a constant magnetic field. This alignment is perturbed by applying a short oscillating field, usually a microwave pulse.
Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spins excited are those of the electrons instead of the atomic nuclei .
To perform a pulsed EDMR experiment, [1] the system is first initialised by placing it in a magnetic field. This orients the spins of the electrons occupying the donor and acceptor in the direction of the magnetic field. To study the donor, we apply a microwave pulse ("γ" in the diagram) at a resonant frequency of the donor. This flips the ...
The electron nuclear distance (R), in meters, along the direction of the interaction is determined by point-dipole approximation. Such approximation takes into account the through-space magnetic interactions of the two magnetic dipoles. Isolation of R gives the distance from the origin (localized unpaired electron) to the spin active nucleus.
In magnetic resonance, a spin echo or Hahn echo is the refocusing of spin magnetisation by a pulse of resonant electromagnetic radiation. [1] Modern nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI) make use of this effect.
In physics and physical chemistry, time-resolved spectroscopy is the study of dynamic processes in materials or chemical compounds by means of spectroscopic techniques.Most often, processes are studied after the illumination of a material occurs, but in principle, the technique can be applied to any process that leads to a change in properties of a material.
Pulsed FT spectrometry gives the advantage of requiring a single, time-dependent measurement which can easily deconvolute a set of similar but distinct signals. The resulting composite signal, is called a free induction decay, because typically the signal will decay due to inhomogeneities in sample frequency, or simply unrecoverable loss of ...
The Self Excited Electron Plasma Resonance Spectroscopy (SEERS) utilizes exactly these nonlinear effects and known resonance effects in RF discharges. The nonlinear elements, in particular the sheaths, provide harmonics in the discharge current and excite the plasma and the sheath at their series resonance characterized by the so-called ...