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The dissociation degree is the fraction of original solute molecules that have dissociated. It is usually indicated by the Greek symbol α. More accurately, degree of dissociation refers to the amount of solute dissociated into ions or radicals per mole.
Raoult's law (/ ˈ r ɑː uː l z / law) is a relation of physical chemistry, with implications in thermodynamics.Proposed by French chemist François-Marie Raoult in 1887, [1] [2] it states that the partial pressure of each component of an ideal mixture of liquids is equal to the vapor pressure of the pure component (liquid or solid) multiplied by its mole fraction in the mixture.
Mole fraction is numerically identical to the number fraction, which is defined as the number of particles of a constituent N i divided by the total number of all molecules N tot. Whereas mole fraction is a ratio of amounts to amounts (in units of moles per moles), molar concentration is a quotient of amount to volume (in units of moles per litre).
Straight lines are drawn from each corner, through the point of interest, to the opposite side of the triangle. The lengths of these lines, as well as the lengths of the segments between the point and the corresponding sides, are measured individually. The ratio of the measured lines then gives the component value as a fraction of 100%.
Hume-Rothery rules, named after William Hume-Rothery, are a set of basic rules that describe the conditions under which an element could dissolve in a metal, forming a solid solution. There are two sets of rules; one refers to substitutional solid solutions, and the other refers to interstitial solid solutions.
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
In thermodynamics, an activity coefficient is a factor used to account for deviation of a mixture of chemical substances from ideal behaviour. [1] In an ideal mixture, the microscopic interactions between each pair of chemical species are the same (or macroscopically equivalent, the enthalpy change of solution and volume variation in mixing is zero) and, as a result, properties of the mixtures ...
Change in volume with increasing ethanol fraction. The molar volume of a substance i is defined as its molar mass divided by its density ρ i 0 : V m , i = M i ρ i 0 {\displaystyle V_{\rm {m,i}}={M_{i} \over \rho _{i}^{0}}} For an ideal mixture containing N components, the molar volume of the mixture is the weighted sum of the molar volumes of ...