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Resolution (chromatography) Example chromatogram showing signal as a function of retention time. In chromatography, resolution is a measure of the separation of two peaks of different retention time t in a chromatogram. [1][2][3][4]
IUPAC definition. The IUPAC definition for resolution in mass spectrometry is. Where a larger resolution indicates a better separation of peaks. [1][2] This definition is used in a number of mass spectrometry texts. [3][4][5][6][7][8][9][10][11] This use is also implied by the term "high-resolution mass spectrometry." [12]
Gas chromatography–mass spectrometry. Gas chromatography–mass spectrometry (GC–MS) is an analytical method that combines the features of gas-chromatography and mass spectrometry to identify different substances within a test sample. [1] Applications of GC–MS include drug detection, fire investigation, environmental analysis, explosives ...
The response factor can be expressed on a molar, volume or mass [1] basis. Where the true amount of sample and standard are equal: = where A is the signal (e.g. peak area) and the subscript i indicates the sample and the subscript st indicates the standard. [2]
The van Deemter equation is a hyperbolic function that predicts that there is an optimum velocity at which there will be the minimum variance per unit column length and, thence, a maximum efficiency. The van Deemter equation was the result of the first application of rate theory to the chromatography elution process.
Time-of-flight mass spectrometry. Time-of-flight mass spectrometry (TOFMS) is a method of mass spectrometry in which an ion 's mass-to-charge ratio is determined by a time of flight measurement. Ions are accelerated by an electric field of known strength. [1] This acceleration results in an ion having the same kinetic energy as any other ion ...
In gas chromatography, the Kovats retention index (shorter Kovats index, retention index; plural retention indices) is used to convert retention times into system-independent constants. The index is named after the Hungarian-born Swiss chemist Ervin Kováts, who outlined the concept in the 1950s while performing research into the composition of ...
A chemist in the 1950s using column chromatography. The Erlenmeyer receptacles are on the floor. Column chromatography in chemistry is a chromatography method used to isolate a single chemical compound from a mixture. Chromatography is able to separate substances based on differential adsorption of compounds to the adsorbent; compounds move ...