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Chemist Linus Pauling first developed the hybridisation theory in 1931 to explain the structure of simple molecules such as methane (CH 4) using atomic orbitals. [2] Pauling pointed out that a carbon atom forms four bonds by using one s and three p orbitals, so that "it might be inferred" that a carbon atom would form three bonds at right angles (using p orbitals) and a fourth weaker bond ...
The carbon–carbon single bond is a sigma bond and is formed between one hybridized orbital from each of the carbon atoms. In ethane , the orbitals are sp 3 - hybridized orbitals, but single bonds formed between carbon atoms with other hybridizations do occur (e.g. sp 2 to sp 2 ).
The central carbon atom is sp-hybridized, and the two terminal carbon atoms are sp 2-hybridized. The bond angle formed by the three carbon atoms is 180°, indicating linear geometry for the central carbon atom. The two terminal carbon atoms are planar, and these planes are twisted 90° from each other.
In organic chemistry, planar, three-connected carbon centers that are trigonal planar are often described as having sp 2 hybridization. [2] [3] Nitrogen inversion is the distortion of pyramidal amines through a transition state that is trigonal planar. Pyramidalization is a distortion of this molecular shape towards a tetrahedral molecular ...
The properties of amorphous carbon films vary depending on the parameters used during deposition. The primary method for characterizing amorphous carbon is through the ratio of sp 2 to sp 3 hybridized bonds present in the material. Graphite consists purely of sp 2 hybridized bonds, whereas diamond consists purely of sp 3 hybridized bonds.
The sp 2-hybridized carbon atoms, which are at their energy minimum in planar graphite, must be bent to form the closed sphere or tube, which produces angle strain. The characteristic reaction of fullerenes is electrophilic addition at 6,6-double bonds, which reduces angle strain by changing sp 2 -hybridized carbons into sp 3 -hybridized ones.
An industrially important example is vinyl chloride, precursor to PVC, [3] a plastic commonly known as vinyl. Chessboard made from polyvinyl chloride. Vinyl is one of the alkenyl functional groups. On a carbon skeleton, sp 2-hybridized carbons or positions are often called vinylic. Allyls, acrylates and styrenics contain vinyl groups.
In particular, Pauling introduced the concept of hybridisation, where atomic s and p orbitals are combined to give hybrid sp, sp 2, and sp 3 orbitals. Hybrid orbitals proved powerful in explaining the molecular geometries of simple molecules like methane, which is tetrahedral with an sp 3 carbon atom and bond angles of 109.5° between the four ...