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Anhydrous aluminium chloride is hygroscopic, having a very pronounced affinity for water. It fumes in moist air and hisses when mixed with liquid water as the Cl − ligands are displaced with H 2 O molecules to form the hexahydrate [Al(H 2 O) 6]Cl 3. The anhydrous phase cannot be regained on heating the hexahydrate.
There are two types of polyisobutene used for this purpose, and they are commonly known as conventional and HR (highly reactive) PIB. Conventional PIB is made by polymerizing Raffinate 1 that contains a mixture of C 4 butenes with aluminum trichloride as catalyst. In comparison, HR PIB is made by polymerizing isobutene using boron trifluoride ...
The first solvation shell of a sodium ion dissolved in water. An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, also known as sodium chloride (NaCl), in water would be represented as Na + (aq) + Cl ...
They range from those of water at very low concentrations approaching 0% HCl to values for fuming hydrochloric acid at over 40% HCl. [31] [32] [33] Hydrochloric acid as the binary (two-component) mixture of HCl and H 2 O has a constant-boiling azeotrope at 20.2% HCl and 108.6 °C (381.8 K; 227.5 °F).
[4] [5] An extended version of this model is used to describe the whole class of hypervalent molecules such as phosphorus pentafluoride and sulfur hexafluoride as well as multi-center π-bonding such as ozone and sulfur trioxide. There are also molecules such as diborane (B 2 H 6) and dialane (Al 2 H 6) which have three-center two-electron bond ...
To clarify that it is the gaseous form that is being referred to, the term anhydrous is prefixed to the name of the substance: Gaseous ammonia is generally referred to as anhydrous ammonia, to distinguish it from its solution in water, household ammonia solution, also known as ammonium hydroxide.
The water molecule is amphoteric in aqueous solution. It can either gain a proton to form a hydronium ion H 3 O +, or else lose a proton to form a hydroxide ion OH −. [7] Another possibility is the molecular autoionization reaction between two water molecules, in which one water molecule acts as an acid and another as a base. H 2 O + H 2 O ...
Two well-known structures are the Zundel cation and the Eigen cation. The Eigen solvation structure has the hydronium ion at the center of an H 9 O + 4 complex in which the hydronium is strongly hydrogen-bonded to three neighbouring water molecules. In the Zundel H 5 O + 2 complex the proton is shared equally by two water molecules in a ...