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Nickel nitrate is the inorganic compound Ni(NO 3) 2 or any hydrate thereof. In the hexahydrate, the nitrate anions are not bonded to nickel. Other hydrates have also been reported: Ni(NO 3) 2. 9H 2 O, Ni(NO 3) 2. 4H 2 O, and Ni(NO 3) 2. 2H 2 O. [3] It is prepared by the reaction of nickel oxide with nitric acid: NiO + 2 HNO 3 + 5 H 2 O → Ni ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
[Ni(NH 3) 6] 2+, like all octahedral nickel(II) complexes, is paramagnetic with two unpaired electrons localized on each Ni center. [Ni(NH 3) 6]Cl 2 is prepared by treating aqueous nickel(II) chloride with ammonia. It is useful as a molecular source of anhydrous nickel(II). [2]
Equivalent weights may be calculated from molar masses if the chemistry of the substance is well known: sulfuric acid has a molar mass of 98.078(5) g mol −1, and supplies two moles of hydrogen ions per mole of sulfuric acid, so its equivalent weight is 98.078(5) g mol −1 /2 eq mol −1 = 49.039(3) g eq −1.
Nickel(II) nitrite is an inorganic compound with the chemical formula Ni(NO 2) 2. [1] Anhydrous nickel nitrite was first discovered in 1961 by Cyril Clifford Addison, who allowed gaseous nickel tetracarbonyl to react with dinitrogen tetroxide, yielding a green smoke. Nickel nitrite was the second transition element anhydrous nitrite discovered ...
tetramethylammonium nickel nitrite TMNIN hexagonal perovskite P 3 m 1, a = 9.103 Å, c = 7.082 Å, V = 508.2 Å 3 , Z = 2, density = 1.770 g/cm 3 ; all nitros are bidentate, nickel either links to N or O of the NO 2 , forming a chain of nickel alternating with ONO
Nickel tungstate can also be prepared by the reaction of nickel(II) oxide and tungsten(VI) oxide. [6] It can also be obtained by the reaction of ammonium metatungstate and nickel(II) nitrate [7] or from the reaction of sodium tungstate, nickel(II) chloride and sodium chloride. [8] Nickel tungstate undergoes a phase transition at 700°C. [5]
The blue isomer is prepared by treating hydrated nickel chloride with triphenylphosphine in alcohols or glacial acetic acid: [1] NiCl 2 •6H 2 O + 2 PPh 3 → NiCl 2 (PPh 3 ) 2 + 6 H 2 O When allowed to crystallise from chlorinated solvents, the tetrahedral isomer converts to the square planar isomer.