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Photoexcitation is the first step in a photochemical process where the reactant is elevated to a state of higher energy, an excited state.The first law of photochemistry, known as the Grotthuss–Draper law (for chemists Theodor Grotthuss and John W. Draper), states that light must be absorbed by a chemical substance in order for a photochemical reaction to take place.
A photon (from Ancient Greek φῶς, φωτός (phôs, phōtós) 'light') is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force.
[4] [5] In this sense, gamma rays, X-rays, microwaves and radio waves are also light. The primary properties of light are intensity, propagation direction, frequency or wavelength spectrum, and polarization. Its speed in vacuum, 299 792 458 m/s, is one of the fundamental constants of nature. [6]
A white light source—emitting light of multiple wavelengths—is focused on a sample (the pairs of complementary colors are indicated by the yellow dotted lines). Upon striking the sample, photons that match the energy gap of the molecules present (green light in this example) are absorbed , exciting the molecules.
Photosensitization is a process of transferring the energy of absorbed light. After absorption, the energy is transferred to the (chosen) reactants. This is part of the work of photochemistry in general. In particular this process is commonly employed where reactions require light sources of certain wavelengths that are not readily available. [14]
In geometrical optics, light is considered to travel in straight lines, while in physical optics, light is considered as an electromagnetic wave. Geometrical optics can be viewed as an approximation of physical optics that applies when the wavelength of the light used is much smaller than the size of the optical elements in the system being ...
Spontaneous emission is the process in which a quantum mechanical system (such as a molecule, an atom or a subatomic particle) transits from an excited energy state to a lower energy state (e.g., its ground state) and emits a quantized amount of energy in the form of a photon. Spontaneous emission is ultimately responsible for most of the light ...
In condensed matter physics, scintillation (/ ˈ s ɪ n t ɪ l eɪ ʃ ən / SIN-til-ay-shun) is the physical process where a material, called a scintillator, emits ultraviolet or visible light under excitation from high energy photons (X-rays or gamma rays) or energetic particles (such as electrons, alpha particles, neutrons, or ions).