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The non-mechanical work of force fields can have either positive or negative sign, work being done by the system on the surroundings, or vice versa. Work done by force fields can be done indefinitely slowly, so as to approach the fictive reversible quasi-static ideal, in which entropy is not created in the system by the process.
In terms of SI base units, one joule corresponds to one kilogram-square metre per square second (1 J = 1 kg⋅m 2 ⋅s −2). One joule is equal to the amount of work done when a force of one newton displaces a body through a distance of one metre in the direction of that force.
Other work terms are added on per system requirements. [11] Each quantity in the equations above can be divided by the amount of substance, measured in moles, to form molar Gibbs free energy. The Gibbs free energy is one of the most important thermodynamic functions for the characterization of a system.
The work per unit of charge is defined as the movement of negligible test charge between two points, and is expressed as the difference in electric potential at those points. The work can be done, for example, by generators, (electrochemical cells) or thermocouples generating an electromotive force.
The SI unit of electric potential energy is joule (named after the English physicist James Prescott Joule). In the CGS system the erg is the unit of energy, being equal to 10 −7 Joules. Also electronvolts may be used, 1 eV = 1.602×10 −19 Joules.
Its published results did much to bring about general acceptance of Joule's work and the kinetic theory. However, in 1848, von Mayer had first had sight of Joule's papers and wrote to the French Académie des Sciences to assert priority. His letter was published in the Comptes Rendus and Joule was quick to react. Thomson's close relationship ...
Quantity (common name/s) (Common) symbol/s Defining equation SI unit Dimension Temperature gradient: No standard symbol K⋅m −1: ΘL −1: Thermal conduction rate, thermal current, thermal/heat flux, thermal power transfer
Reflecting the experimental work of Mayer and of Joule, Clausius wrote: In all cases in which work is produced by the agency of heat, a quantity of heat is consumed which is proportional to the work done; and conversely, by the expenditure of an equal quantity of work an equal quantity of heat is produced. [17]