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The saponification value is the amount of base required to saponify a fat sample. [3] Soap makers formulate their recipes with a small deficit of lye to account for the unknown deviation of saponification value between their oil batch and laboratory averages.
Example of saponification reaction of a triglyceride molecule (left) with potassium hydroxide (KOH) yielding glycerol (purple) and salts of fatty acids ().. Saponification value or saponification number (SV or SN) represents the number of milligrams of potassium hydroxide (KOH) or sodium hydroxide (NaOH) required to saponify one gram of fat under the conditions specified.
The meltable base is usually naturally rich in glycerine, a by-product of saponification that has humectant and emollient properties, whereas commercial soap bars have often had this component removed. As with the rebatching method, it can be considered a misnomer to refer to the melt and pour process as soap making. The process has much in ...
The principal historical use of these plants was boiling down to make soap. Saponaria officinalis is most suited for this procedure, but other related species also work. The greatest concentration of saponin occurs during flowering, with the most saponin found in the woody stems and roots, but the leaves also contain some.
Perhaps the oldest commercially practiced example of ester hydrolysis is saponification (formation of soap). It is the hydrolysis of a triglyceride (fat) with an aqueous base such as sodium hydroxide (NaOH). During the process, glycerol is formed, and the fatty acids react with the base, converting them to salts. These salts are called soaps ...
Total fatty matter (TFM) is one of the most important characteristics describing the quality of soap and is always specified in commercial transactions. It is defined as the total amount of fatty matter, mostly fatty acids, that can be separated from a sample after splitting with a mineral acid, usually hydrochloric acid.
Action of soap on oil. When surfactants are present above the critical micelle concentration (CMC), they can act as emulsifiers that will allow a compound that is normally insoluble (in the solvent being used) to dissolve. This occurs because the insoluble species can be incorporated into the micelle core, which is itself solubilized in the ...
Alkaline hydrolysis of esters is also known as saponification. A base such as sodium hydroxide is required in stochiometric amounts. Unlike acid-catalyzed ester hydrolysis, it is not an equilibrium reaction and proceeds to completion.