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Iron shows the characteristic chemical properties of the transition metals, namely the ability to form variable oxidation states differing by steps of one and a very large coordination and organometallic chemistry: indeed, it was the discovery of an iron compound, ferrocene, that revolutionalized the latter field in the 1950s. [59]
Iron shows the characteristic chemical properties of the transition metals, namely the ability to form variable oxidation states differing by steps of one and a very large coordination and organometallic chemistry: indeed, it was the discovery of an iron compound, ferrocene, that revolutionalized the latter field in the 1950s. [1]
Iron(II) chloride tetrahydrate, FeCl 2 ·4H 2 O. In chemistry, iron(II) refers to the element iron in its +2 oxidation state. The adjective ferrous or the prefix ferro-is often used to specify such compounds, as in ferrous chloride for iron(II) chloride (FeCl 2). The adjective ferric is used instead for iron(III) salts, containing the cation Fe 3+.
Rust is an iron oxide, a usually reddish-brown oxide formed by the reaction of iron and oxygen in the catalytic presence of water or air moisture.Rust consists of hydrous iron(III) oxides (Fe 2 O 3 ·nH 2 O) and iron(III) oxide-hydroxide (FeO(OH), Fe(OH) 3), and is typically associated with the corrosion of refined iron.
Iron oxides and oxyhydroxides are widespread in nature and play an important role in many geological and biological processes. They are used as iron ores, pigments, catalysts, and in thermite, and occur in hemoglobin. Iron oxides are inexpensive and durable pigments in paints, coatings and colored concretes.
Mill scale is a complex oxide that contains around 70% iron with traces of nonferrous metals and alkaline compounds. Reduced iron powder may be obtained by conversion of mill scale into a single highest oxide i.e. hematite (Fe 2 O 3) followed by reduction with hydrogen.
In industry, iron(III) chloride is used as a catalyst for the reaction of ethylene with chlorine, forming ethylene dichloride (1,2-dichloroethane): [43] H 2 C=CH 2 + Cl 2 → ClCH 2 CH 2 Cl. Ethylene dichloride is a commodity chemical, which is mainly used for the industrial production of vinyl chloride, the monomer for making PVC. [44]
Iron(II) oxide or ferrous oxide is the inorganic compound with the formula FeO. Its mineral form is known as wüstite . [ 3 ] [ 4 ] One of several iron oxides , it is a black-colored powder that is sometimes confused with rust , the latter of which consists of hydrated iron(III) oxide (ferric oxide).