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Random errors are errors in measurement that lead to measurable values being inconsistent when repeated measurements of a constant attribute or quantity are taken. Random errors create measurement uncertainty .
Any non-linear differentiable function, (,), of two variables, and , can be expanded as + +. If we take the variance on both sides and use the formula [11] for the variance of a linear combination of variables (+) = + + (,), then we obtain | | + | | +, where is the standard deviation of the function , is the standard deviation of , is the standard deviation of and = is the ...
If the instrument has a needle which points to a scale graduated in steps of 0.1 units, then depending on the design of the instrument, it is usually possible to estimate tenths between the successive marks on the scale, so it should be possible to read off the result to an accuracy of about 0.01 units.
While precision is a description of random errors (a measure of statistical variability), accuracy has two different definitions: More commonly, a description of systematic errors (a measure of statistical bias of a given measure of central tendency, such as the mean). In this definition of "accuracy", the concept is independent of "precision ...
This is a list of unsolved problems in chemistry. Problems in chemistry are considered unsolved when an expert in the field considers it unsolved or when several experts in the field disagree about a solution to a problem.
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The statistical errors, on the other hand, are independent, and their sum within the random sample is almost surely not zero. One can standardize statistical errors (especially of a normal distribution ) in a z-score (or "standard score"), and standardize residuals in a t -statistic , or more generally studentized residuals .
The Westgard rules are a set of statistical patterns, each being unlikely to occur by random variability, thereby raising a suspicion of faulty accuracy or precision of the measurement system. They are used for laboratory quality control , in "runs" consisting of measurements of multiple samples.