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The path between each state consists of some process (A through D) which alters the pressure or volume of the system (or both). Generalized PV diagram. A key feature of the diagram is that the amount of energy expended or received by the system as work can be measured because the net work is represented by the area enclosed by the four lines ...
Dr. A.P.J. Abdul Kalam Technical University, Lucknow formerly known as Uttar Pradesh Technical University (UPTU), was established by the government of Uttar Pradesh on 8 May 2000 (Act No. 1248 (2)XVII-V-I-I-19-2000 Uttar Pradesh Adhiniyam Sankhya 23 of 2000).
The pressure on a pressure-temperature diagram (such as the water phase diagram shown above) is the partial pressure of the substance in question. A phase diagram in physical chemistry , engineering , mineralogy , and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct ...
Thermodynamic diagrams are diagrams used to represent the thermodynamic states of a material (typically fluid) and the consequences of manipulating this material. For instance, a temperature– entropy diagram ( T–s diagram ) may be used to demonstrate the behavior of a fluid as it is changed by a compressor.
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The figure at right shows a block diagram of a generic heat engine, such as the Carnot engine. In the diagram, the "working body" (system), a term introduced by Clausius in 1850, can be any fluid or vapor body through which heat Q can be introduced or transmitted to produce work. Carnot had postulated that the fluid body could be any substance ...
If at every point in the cycle the system is in thermodynamic equilibrium, the cycle is reversible. Whether carried out reversible or irreversibly, the net entropy change of the system is zero, as entropy is a state function. During a closed cycle, the system returns to its original thermodynamic state of temperature and pressure.
Pressure–volume work (or PV or P-V work) occurs when the volume V of a system changes. PV work is often measured in units of litre-atmospheres where 1 L·atm = 101.325 J. However, the litre-atmosphere is not a recognized unit in the SI system of units, which measures P in pascals (Pa), V in m 3, and PV in joules (J), where 1 J = 1 Pa·m 3.