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In the last column, major departures of solids at standard temperatures from the Dulong–Petit law value of 3 R, are usually due to low atomic weight plus high bond strength (as in diamond) causing some vibration modes to have too much energy to be available to store thermal energy at the measured temperature.
The expanded graphite can be used to make graphite foil or used directly as a "hot top" compound to insulate molten metal in a ladle or red-hot steel ingots and decrease heat loss, or as firestops fitted around a fire door or in sheet metal collars surrounding plastic pipe (during a fire, the graphite expands and chars to resist fire ...
This is essentially different from results of potassium intercalation in graphite or C60 fullerene, and shows that sp3 bonding promotes magnetic ordering in carbon. The measurements presented first experimental evidence of intercalation-induced spin-glass state in a nanocrystalline diamond system.
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Graphite, a 3D counterpart to graphene, exhibits a basal plane thermal conductivity exceeding 1000 W⋅m −1 ⋅K −1 (similar to diamond), In graphite, the c-axis (out of plane) thermal conductivity is over a factor of ~100 smaller due to the weak binding forces between basal planes as well as the larger lattice spacing. [179]
At standard temperature and pressure, 20 °C (293 K) and 1 standard atmosphere (0.10 MPa), the stable phase of carbon is graphite, but diamond is metastable, with a significant kinetic energy barrier that the atoms must overcome in order to reach the lower energy state, [12] and its rate of conversion to graphite is negligible, with a timescale ...
In 2001, a diamond-like-structured c-BC 2 N was synthesized at pressures >18 GPa and temperatures >2,200 K by a direct solid-state phase transition of graphite-like (BN) 0.48 C 0.52. The reported Vickers and Knoop hardnesses were intermediate between diamond and c-BN, making the new phase the second hardest known material. [39]
The density of states related to volume V and N countable energy levels is defined as: = = (()). Because the smallest allowed change of momentum for a particle in a box of dimension and length is () = (/), the volume-related density of states for continuous energy levels is obtained in the limit as ():= (()), Here, is the spatial dimension of the considered system and the wave vector.