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In aqueous solution, ammonia deprotonates a small fraction of the water to give ammonium and hydroxide according to the following equilibrium: . NH 3 + H 2 O ⇌ NH + 4 + OH −.. In a 1 M ammonia solution, about 0.42% of the ammonia is converted to ammonium, equivalent to pH = 11.63 because [NH +
Amines can be formed by the reaction of ammonia with alkyl halides or, more commonly, with alcohols: CH 3 OH + NH 3 → CH 3 NH 2 + H 2 O. Its ring-opening reaction with ethylene oxide give ethanolamine, diethanolamine, and triethanolamine. Amides can be prepared by the reaction of ammonia with carboxylic acid and their derivatives.
Walsh diagrams in conjunction with molecular orbital theory can also be used as a tool to predict reactivity. By generating a Walsh Diagram and then determining the HOMO/LUMO of that molecule, it can be determined how the molecule is likely to react. In the following example, the Lewis acidity of AH 3 molecules such as BH 3 and CH 3 + is predicted.
The hydrogen atoms in the ammonium ion can be substituted with an alkyl group or some other organic group to form a substituted ammonium ion (IUPAC nomenclature: aminium ion). Depending on the number of organic groups, the ammonium cation is called a primary, secondary, tertiary, or quaternary. Except the quaternary ammonium cations, the ...
The Haber process, [5] also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. [6] [7] It converts atmospheric nitrogen (N 2) to ammonia (NH 3) by a reaction with hydrogen (H 2) using finely divided iron metal as a catalyst:
The molecular geometry can be determined by various spectroscopic methods and diffraction methods. IR, microwave and Raman spectroscopy can give information about the molecule geometry from the details of the vibrational and rotational absorbance detected by these techniques.
Enantiomers can be separated by chiral resolution. This often involves forming crystals of a salt composed of one of the enantiomers and an acid or base from the so-called chiral pool of naturally occurring chiral compounds, such as malic acid or the amine brucine. Some racemic mixtures spontaneously crystallize into right-handed and left ...
Phosphorus pentoxide chemical structure in 2D. A chemical structure of a molecule is a spatial arrangement of its atoms and their chemical bonds. Its determination includes a chemist's specifying the molecular geometry and, when feasible and necessary, the electronic structure of the target molecule or other solid.