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If magnesium chloride (or sulfate) is treated with aqueous sodium carbonate, a precipitate of basic magnesium carbonate – a hydrated complex of magnesium carbonate and magnesium hydroxide – rather than magnesium carbonate itself is formed: 5 MgCl 2 (aq) + 5 Na 2 CO 3 (aq) + 5 H 2 O(l) → Mg 4 (CO 3) 3 (OH) 2 ·3H 2 O(s) + Mg(HCO 3) 2 (aq ...
Artinite is a hydrated basic magnesium carbonate mineral with formula: Mg 2 (CO 3)(OH) 2 ·3H 2 O. It forms white silky monoclinic prismatic crystals that are often in radial arrays or encrustations. It has a Mohs hardness of 2.5 and a specific gravity of 2.
It is the most common cave carbonate after calcite and aragonite. [2] The mineral thermally decomposes, [5] [6] over a temperature range of approximately 220 °C to 550 °C, releasing water and carbon dioxide leaving a magnesium oxide residue. Hydromagnesite was first described in 1836 for an occurrence in Hoboken, New Jersey. [3]
Magnesium hypochlorite and magnesium chlorite are unstable compounds, they are easy to hydrolyze, the former generates basic salt Mg(OCl) 2 ·2Mg(OH) 2 and the latter generates hydroxide Mg(OH) 2; magnesium chlorate can be obtained by reacting magnesium carbonate with chloric acid and crystallizing hexahydrate from solution, which can also be ...
Magnesite can also be formed via the carbonation of magnesium serpentine (lizardite) via the following reaction: 2 Mg 3 Si 2 O 5 (OH) 4 + 3 CO 2 → Mg 3 Si 4 O 10 (OH) 2 + 3 MgCO 3 + 3 H 2 O. However, when performing this reaction in the laboratory, the trihydrated form of magnesium carbonate (nesquehonite) will form at room temperature. [6]
It represents the pentahydrate of magnesium carbonate, and has the total formula MgCO 3 ·5H 2 O . [2] Landsfordite was discovered in 1888 in a coal mine in Lansford, Pennsylvania. It crystallizes in the monoclinic system (space group P2 1 /c [3]) and typically occurs as colorless to white prismatic crystals and stalactitic masses. [4]
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Magnesium reacts with haloalkanes to give Grignard reagents, which are used for a wide variety of organic reactions forming carbon–carbon bonds. [99] Magnesium salts are included in various foods, [100] fertilizers [101] (magnesium is a component of chlorophyll [102]), and microbe culture media. [103]