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Phosgene is an organic chemical compound with the formula COCl 2. It is a toxic, colorless gas; in low concentrations, its musty odor resembles that of freshly cut ...
Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula P H 3, classed as a pnictogen hydride. Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and diphosphane ( P 2 H 4 ).
German phosgene came in the form of diphosgene, codenamed Grün Kreuz (Green cross). This was less effective than its allied counterpart, being less toxic and slower to evaporate, but was easier to handle in shell manufacture early in the war. [35] Phosgene was a potent killing agent, deadlier than chlorine.
Phosphines or phosphanes are phosphorus compounds derived from phosphine and have the general structure R 3 P. For the nitrogen analogues, please see Category:Inorganic amines . Wikimedia Commons has media related to Phosphines .
Compounds related to phosphine oxides include phosphine imides (R 3 PNR') and related chalcogenides (R 3 PE, where E = S, Se, Te). These compounds are some of the most thermally stable organophosphorus compounds. In general, they are less basic than the corresponding phosphine oxides, which can adduce to thiophosphoryl halides: [7]: 73
The reaction with oxygen is spin-forbidden but still proceeds at sufficient rate that samples of tertiary phosphines are characteristically contaminated with phosphine oxides. Qualitatively, the rates of oxidation are higher for trialkyl vs triarylphosphines. Faster still are oxidations using hydrogen peroxide. Primary and secondary phosphines ...
That day, in August 2013, Patrick got in the car and put the duffel bag on a seat. Inside was a talisman he’d been given by the treatment facility: a hardcover fourth edition of the Alcoholics Anonymous bible known as “The Big Book.”
Green Cross (Grünkreuz) is a World War I chemical warfare pulmonary agent consisting of chloropicrin (PS, Aquinite, Klop), phosgene (CG, Collongite) and/or trichloromethyl chloroformate (Surpalite, Perstoff). Green Cross is also a generic World War I German marking for artillery shells with pulmonary agents (chemical payload affecting the ...