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  2. Matrix (chemical analysis) - Wikipedia

    en.wikipedia.org/wiki/Matrix_(chemical_analysis)

    For example, the ionic strength of the solution can have an effect on the activity coefficients of the analytes. [3] [4] The most common approach for accounting for matrix effects is to build a calibration curve using standard samples with known analyte concentration and which try to approximate the matrix of the sample as much as possible. [2]

  3. Standard solution - Wikipedia

    en.wikipedia.org/wiki/Standard_solution

    Standard solutions are generally prepared by dissolving a solute of known mass into a solvent to a precise volume, or by diluting a solution of known concentration with more solvent. [1] A standard solution ideally has a high degree of purity and is stable enough that the concentration can be accurately measured after a long shelf time. [2]

  4. Sample preparation in mass spectrometry - Wikipedia

    en.wikipedia.org/wiki/Sample_preparation_in_mass...

    Sample preparation for mass spectrometry is used for the optimization of a sample for analysis in a mass spectrometer (MS). Each ionization method has certain factors that must be considered for that method to be successful, such as volume, concentration, sample phase, and composition of the analyte solution. Quite possibly the most important ...

  5. Orsat gas analyser - Wikipedia

    en.wikipedia.org/wiki/Orsat_gas_analyser

    An Orsat gas analyser or Orsat apparatus is a piece of laboratory equipment used to analyse a gas sample (typically fossil fuel flue gas) for its oxygen, carbon monoxide and carbon dioxide content. Although largely replaced by instrumental techniques, the Orsat remains a reliable method of measurement and is relatively simple to use.

  6. Standard addition - Wikipedia

    en.wikipedia.org/wiki/Standard_addition

    Outside the field of polarography, Harvey's book Spectrochemical Procedures was the next earliest reference book to mention standard addition. [4] Harvey's approach, which involves the successive addition of standards, closely resembles the most commonly used method of standard addition today.

  7. Winkler titration - Wikipedia

    en.wikipedia.org/wiki/Winkler_titration

    The second part of the Winkler test reduces (acidifies) the solution. The precipitate will dissolve back into solution as the H + reacts with the O 2− and OH − to form water. MnO(OH) 2 (s) + 4 H + (aq) → Mn 4+ (aq) + 3 H 2 O(l) The acid facilitates the conversion by the brown, Manganese-containing precipitate of the Iodide ion into ...

  8. Calibration curve - Wikipedia

    en.wikipedia.org/wiki/Calibration_curve

    A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]

  9. Titration - Wikipedia

    en.wikipedia.org/wiki/Titration

    Titration (also known as titrimetry [1] and volumetric analysis) is a common laboratory method of quantitative chemical analysis to determine the concentration of an identified analyte (a substance to be analyzed). A reagent, termed the titrant or titrator, [2] is prepared as a standard solution of known concentration and volume.

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