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Intensive properties are material characteristics and are not dependent on the size or extent of the sample. Commonly quoted and tabulated in the literature are the specific latent heat of fusion and the specific latent heat of vaporization for many substances. From this definition, the latent heat for a given mass of a substance is calculated by
The Bowen ratio is calculated by the equation: =, where is sensible heating and is latent heating. In this context, when the magnitude of is less than one, a greater proportion of the available energy at the surface is passed to the atmosphere as latent heat than as sensible heat, and the converse is true for values of greater than one.
For example, if the gas expands slowly against the piston, the work done by the gas to raise the piston is the force F times the distance d. But the force is just the pressure P of the gas times the area A of the piston, F = PA. [4] Thus W = Fd; W = PAd; W = P(V 2 − V 1) figure 3
Calorimetry requires that a reference material that changes temperature have known definite thermal constitutive properties. The classical rule, recognized by Clausius and Kelvin, is that the pressure exerted by the calorimetric material is fully and rapidly determined solely by its temperature and volume; this rule is for changes that do not involve phase change, such as melting of ice.
The caloric theory is an obsolete scientific theory that heat consists of a self-repellent fluid called caloric that flows from hotter bodies to colder bodies. Caloric was also thought of as a weightless gas that could pass in and out of pores in solids and liquids.
In a statistical mechanical account of an ideal gas, in which the molecules move independently between instantaneous collisions, the internal energy is just the sum total of the gas's independent particles' kinetic energies, and it is this kinetic motion that is the source and the effect of the transfer of heat across a system's boundary.
In systems involving heat transfer, a condenser is a heat exchanger used to condense a gaseous substance into a liquid state through cooling. In doing so, the latent heat is released by the substance and transferred to the surrounding environment. Condensers are used for efficient heat rejection in many industrial systems.
For example as radiant energy warms a body of water it raises the temperature generating sensible heat. Water evaporated from the body of water changes state as latent heat. [17] To change one gram of liquid water to vapour requires 540 calories of heat, and if that water vapour condenses back to liquid water 540 calories are released. [17]