Search results
Results from the WOW.Com Content Network
In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...
In chemistry, a (redox) non-innocent ligand is a ligand in a metal complex where the oxidation state is not clear. Typically, complexes containing non-innocent ligands are redox active at mild potentials. The concept assumes that redox reactions in metal complexes are either metal or ligand localized, which is a simplification, albeit a useful ...
Example of a reduction–oxidation reaction between sodium and chlorine, with the OIL RIG mnemonic [1] Redox (/ ˈ r ɛ d ɒ k s / RED-oks, / ˈ r iː d ɒ k s / REE-doks, reduction–oxidation [2] or oxidation–reduction [3]: 150 ) is a type of chemical reaction in which the oxidation states of the reactants change. [4]
The difference between the current that is actually obtained, at any particular value of the potential of the indicator or working electrode, for the reduction or oxidation of an ionic electroactive substance and the current that would be obtained, at the same potential, if there were no transport of that substance due to the electric field between the electrodes.
In aqueous solutions, redox potential is a measure of the tendency of the solution to either gain or lose electrons in a reaction. A solution with a higher (more positive) reduction potential than some other molecule will have a tendency to gain electrons from this molecule (i.e. to be reduced by oxidizing this other molecule) and a solution with a lower (more negative) reduction potential ...
The overall chemical reaction taking place in a cell is made up of two independent half-reactions, which describe chemical changes at the two electrodes. To focus on the reaction at the working electrode, the reference electrode is standardized with constant (buffered or saturated) concentrations of each participant of the redox reaction. [1]
A fundamental difference between redox reactions in batteries and in electrochemical capacitors (supercapacitors) is that in the latter, the reactions are a very fast sequence of reversible processes with electron transfer without any phase changes of the electrode molecules. They do not involve making or breaking chemical bonds.
For example, the equivalent weight of oxygen is 16.0/2 = 8.0 grams. For acid–base reactions, the equivalent weight of an acid or base is the mass which supplies or reacts with one mole of hydrogen cations (H +). For redox reactions, the equivalent weight of each reactant supplies or reacts with one mole of electrons (e −) in a redox ...