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It is related to tetrahydrofuran (THF) by replacement of the methylene group (CH 2) at the 2-position with an oxygen atom. The corresponding saturated 6-membered C 4 O 2 rings are called dioxanes. The isomeric 1,2-dioxolane (wherein the two oxygen centers are adjacent) is a peroxide. 1,3-dioxolane is used as a solvent and as a comonomer in ...
2-Bromoethyl ether (or Bis(2-bromoethyl) ether) is an organobromine compound that is also an ether. It is used in the manufacture of pharmaceuticals and crown ethers . [ 1 ] [ 2 ] [ 3 ]
Synthesis methods for the 1,2-dioxolane core structure include oxidation of cyclopropane derivatives with singlet oxygen [3] or molecular oxygen with a suitable catalyst, [4] [5] the use of autooxidation, nucleophilic displacement with hydrogen peroxide, treatment with mercury(II) nitrate, photolysis of extended π-systems, [6] reaction of a bis-silylperoxide and an alkene, [7] or reaction ...
A series of studies have shown that bromophenols derived from brominated flame retardants (BFRs) in human environments are present in human blood and breast milk. [1] Bromophenols (as well as PBDEs ) were detected in 88% of samples, with 2,4,6-Tribromophenol present in 84% of breast milk samples alone.
1,3-Dioxane or m-dioxane is an organic compound with the molecular formula (CH 2) 4 O 2. It is a saturated six-membered heterocycle with two oxygen atoms in place of carbon atoms at the 1- and 3- positions. 1,4-Dioxane, which is of greater commercial value, is an isomer. Both dioxanes are colorless liquids. [1]
Disarming sugars can also be accomplished by adding 1,3-dioxane and 1,3-dioxolane protecting groups onto sugars. These protecting groups “lock” the sugars into a rigid chair conformation. When the sugar forms the necessary oxocarbenium ion, it flattens at the anomeric position.
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One of the bromine substituents is converted to an aldehyde through an S N 2 reaction with the strong base, n-BuLi, and THF in the aprotic polar solvent, DMF to produce 2,5-bis(4-tert-butyldimethylsiloxy-1′-butynyl)-4-bromobenzaldehyde. Another Sonogashira coupling with 3,5-(1′-Pentynyl)-1-ethynylbenzene attaches the lower body of the ...