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The strain energy in the form of elastic deformation is mostly recoverable in the form of mechanical work. For example, the heat of combustion of cyclopropane (696 kJ/mol) is higher than that of propane (657 kJ/mol) for each additional CH 2 unit. Compounds with unusually large strain energy include tetrahedranes, propellanes, cubane-type ...
Castigliano's method for calculating displacements is an application of his second theorem, which states: If the strain energy of a linearly elastic structure can be expressed as a function of generalised force Q i then the partial derivative of the strain energy with respect to generalised force gives the generalised displacement q i in the direction of Q i.
For an isotropic hyperelastic material, the function relates the energy stored in an elastic material, and thus the stress–strain relationship, only to the three strain (elongation) components, thus disregarding the deformation history, heat dissipation, stress relaxation etc.
Strain energy density consists of two components - volumetric or dialational and distortional. Volumetric component is responsible for change in volume without any change in shape. Distortional component is responsible for shear deformation or change in shape.
There are situations where seemingly identical conformations are not equal in strain energy. Syn-pentane strain is an example of this situation. There are two different ways to put both of the bonds the central in n-pentane into a gauche conformation, one of which is 3 kcal mol −1 higher in energy than the other. [1]
The primary, and likely most widely employed, strain-energy function formulation is the Mooney–Rivlin model, which reduces to the widely known neo-Hookean model. The strain energy density function for an incompressible Mooney–Rivlin material is = + (); =
The most common example of this kind of material is rubber, whose stress-strain relationship can be defined as non-linearly elastic, isotropic and incompressible. Hyperelasticity provides a means of modeling the stress–strain behavior of such materials. [2] The behavior of unfilled, vulcanized elastomers often conforms closely to the ...
In continuum mechanics, the infinitesimal strain theory is a mathematical approach to the description of the deformation of a solid body in which the displacements of the material particles are assumed to be much smaller (indeed, infinitesimally smaller) than any relevant dimension of the body; so that its geometry and the constitutive properties of the material (such as density and stiffness ...