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The energy spectrum of a system with such discrete energy levels is said to be quantized. In chemistry and atomic physics, an electron shell, or principal energy level, may be thought of as the orbit of one or more electrons around an atom's nucleus. The closest shell to the nucleus is called the "1 shell" (also called "K shell"), followed by ...
In 1901, when Max Planck was developing the distribution function of statistical mechanics to solve the ultraviolet catastrophe problem, he realized that the properties of blackbody radiation can be explained by the assumption that the amount of energy must be in countable fundamental units, i.e. amount of energy is not continuous but discrete.
In the case of degenerate energy levels, we can write the partition function in terms of the contribution from energy levels (indexed by j) as follows: =, where g j is the degeneracy factor, or number of quantum states s that have the same energy level defined by E j = E s.
If level 1 is the lower energy level with energy E 1, and level 2 is the upper energy level with energy E 2, then the frequency ν of the radiation radiated or absorbed will be determined by Bohr's frequency condition: [35] [36] =.
A ladder of quantized energy levels, called the Jaynes–Cummings ladder, that scales in energy non-linearly as where is the total number of quanta in the coupled system. This quantization of energies and non-linear scaling is purely quantum mechanical in nature.
The macroscopic energy equation for infinitesimal volume used in heat transfer analysis is [6] = +, ˙, where q is heat flux vector, −ρc p (∂T/∂t) is temporal change of internal energy (ρ is density, c p is specific heat capacity at constant pressure, T is temperature and t is time), and ˙ is the energy conversion to and from thermal ...
In 1900, Max Planck derived the average energy ε of a single energy radiator, e.g., a vibrating atomic unit, as a function of absolute temperature: [24] = / (), where h is the Planck constant, ν is the frequency, k is the Boltzmann constant, and T is the absolute temperature. The zero-point energy makes no contribution to Planck's original ...
The term "entropy" has been in use from early in the history of classical thermodynamics, and with the development of statistical thermodynamics and quantum theory, entropy changes have been described in terms of the mixing or "spreading" of the total energy of each constituent of a system over its particular quantized energy levels.