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For example, the electron configuration of the titanium ground state can be written as either [Ar] 4s 2 3d 2 or [Ar] 3d 2 4s 2. The first notation follows the order based on the Madelung rule for the configurations of neutral atoms; 4s is filled before 3d in the sequence Ar, K, Ca, Sc, Ti.
However there are numerous exceptions; for example the lightest exception is chromium, which would be predicted to have the configuration 1s 2 2s 2 2p 6 3s 2 3p 6 3d 4 4s 2, written as [Ar] 3d 4 4s 2, but whose actual configuration given in the table below is [Ar] 3d 5 4s 1.
For example, the first (K) shell has one subshell, called 1s; the second (L) shell has two subshells, called 2s and 2p; the third shell has 3s, 3p, and 3d; the fourth shell has 4s, 4p, 4d and 4f; the fifth shell has 5s, 5p, 5d, and 5f and can theoretically hold more in the 5g subshell that is not occupied in the ground-state electron ...
For example, in copper 29 Cu, according to the Madelung rule, the 4s subshell (n + l = 4 + 0 = 4) is occupied before the 3d subshell (n + l = 3 + 2 = 5). The rule then predicts the electron configuration 1s 2 2s 2 2p 6 3s 2 3p 6 3d 9 4s 2, abbreviated [Ar] 3d 9 4s 2 where [Ar] denotes the configuration of argon, the preceding noble gas.
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Og, 118, oganesson : 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 3d 10 4p 6 5s 2 4d 10 5p 6 6s 2 4f 14 5d 10 6p 6 7s 2 5f 14 6d 10 7p 6 Note that these electron configurations are given for neutral atoms in the gas phase, which are not the same as the electron configurations for the same atoms in chemical environments.
Starting the next row, for potassium and calcium the 4s subshell is the lowest in energy, and therefore they fill it. [39] [58] Potassium adds one electron to the 4s shell ([Ar] 4s 1), and calcium then completes it ([Ar] 4s 2). However, starting from scandium ([Ar] 3d 1 4s 2) the 3d subshell becomes the next highest in energy. The 4s and 3d ...
An example provided in Slater's original paper is for the iron atom which has nuclear charge 26 and electronic configuration 1s 2 2s 2 2p 6 3s 2 3p 6 3d 6 4s 2.The screening constant, and subsequently the shielded (or effective) nuclear charge for each electron is deduced as: [1]