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The electrochemical reduction of carbon dioxide, also known as CO2RR, is the conversion of carbon dioxide (CO 2) to more reduced chemical species using electrical energy. It represents one potential step in the broad scheme of carbon capture and utilization. [1]
Thermodynamic potentials for the reduction of CO 2 to various products is given in the following table versus NHE at pH = 7. Single electron reduction of CO 2 to CO 2 − radical occurs at E° = −1.90 V versus NHE at pH = 7 in an aqueous solution at 25 °C under 1 atm gas pressure.
1 Table of standard electrode potentials. 2 See also. ... and the Faraday constant F is the conversion factor describing Coulombs transferred per mole electrons ...
Other photosensitizers have also been employed as catalysts. They include FeTPP (TPP=5,10,15,20-tetraphenyl-21H,23H-porphine) and CoTPP, both of which produce CO while the latter produces formate also. Non-metal photocatalysts include pyridine and N-heterocyclic carbenes. [7] [8] A reaction scheme for the catalytic reduction of CO 2 by Re(bpy ...
The concentration of carbon dioxide (CO 2) in the atmosphere reached 427 ppm (0.0427%) on a molar basis in 2024, representing 3341 gigatonnes of CO 2. [78] This is an increase of 50% since the start of the Industrial Revolution, up from 280 ppm during the 10,000 years prior to the mid-18th century. [79] [80] [81] The increase is due to human ...
It is the disproportionation of carbon monoxide into carbon dioxide and graphite or its reverse: [1] 2CO ⇌ CO 2 + C Boudouard-Equilibrium at 1 bar calculated with 2 different methods Standard enthalpy of the Boudouard reaction at various temperatures. The Boudouard reaction to form carbon dioxide and carbon is exothermic at all
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Carbon dioxide (CO 2) can be reduced to carbon monoxide (CO) and other more reduced compounds, such as methane, using the appropriate photocatalysts. One early example was the use of Tris(bipyridine)ruthenium(II) chloride (Ru(bipy) 3 Cl 2) and cobalt chloride (CoCl 2) for CO 2 reduction to CO. [27]