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  2. Enthalpy change of solution - Wikipedia

    en.wikipedia.org/wiki/Enthalpy_change_of_solution

    The energy released by the solvation of the ammonium ions and nitrate ions is less than the energy absorbed in breaking up the ammonium nitrate ionic lattice and the attractions between water molecules. Dissolving potassium hydroxide is exothermic, as more energy is released during solvation than is used in breaking up the solute and solvent.

  3. Chemical thermodynamics - Wikipedia

    en.wikipedia.org/wiki/Chemical_thermodynamics

    Chemical energy is the energy that can be released when chemical substances undergo a transformation through a chemical reaction. Breaking and making chemical bonds involves energy release or uptake, often as heat that may be either absorbed by or evolved from the chemical system.

  4. Enthalpy - Wikipedia

    en.wikipedia.org/wiki/Enthalpy

    Enthalpy (/ ˈ ɛ n θ əl p i / ⓘ) is the sum of a thermodynamic system's internal energy and the product of its pressure and volume. [1] It is a state function in thermodynamics used in many measurements in chemical, biological, and physical systems at a constant external pressure, which is conveniently provided by the large ambient atmosphere.

  5. Thermodynamic activity - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_activity

    The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.

  6. Gibbs free energy - Wikipedia

    en.wikipedia.org/wiki/Gibbs_free_energy

    In thermodynamics, the Gibbs free energy (or Gibbs energy as the recommended name; symbol ) is a thermodynamic potential that can be used to calculate the maximum amount of work, other than pressure–volume work, that may be performed by a thermodynamically closed system at constant temperature and pressure.

  7. Helmholtz free energy - Wikipedia

    en.wikipedia.org/wiki/Helmholtz_free_energy

    In thermodynamics, the Helmholtz free energy (or Helmholtz energy) is a thermodynamic potential that measures the useful work obtainable from a closed thermodynamic system at a constant temperature . The change in the Helmholtz energy during a process is equal to the maximum amount of work that the system can perform in a thermodynamic process ...

  8. Chemical equilibrium - Wikipedia

    en.wikipedia.org/wiki/Chemical_equilibrium

    The standard Gibbs energy change, together with the Gibbs energy of mixing, determine the equilibrium state. [8] [9] In this article only the constant pressure case is considered. The relation between the Gibbs free energy and the equilibrium constant can be found by considering chemical potentials. [1]

  9. Chemical potential - Wikipedia

    en.wikipedia.org/wiki/Chemical_potential

    In thermodynamics, the chemical potential of a species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition.