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When atmospheric carbon dioxide (CO 2), or carbonate ions (HCO − 3, CO 2− 3 dissolved in water) diffuse into concrete from its external surface, they react with calcium hydroxide (portlandite, Ca(OH) 2) and the pH of the concrete pore water progressively decreases from 13.5 – 12.5 to 8.5 (pH of water in equilibrium with calcite).
Test methods for the water-cement ratio and fineness modulus). 1919 – Effect of Curing Condition on Wear and Strength of Concrete (Describing 120 tests on cylinder-shaped samples and 300 tests on cubic samples in various moisture conditions and testing periods varying from 3 days to 4 months).
When the carbonation front reaches the steel reinforcements (rebar), the pH of the concrete pore water at the steel surface decreases. At a pH value lower than 10.5, the carbon steel is no longuer passivated by an alkaline pH and starts to corrode (general corrosion). A faster diffusion of oxygen (O
Acid-neutralizing capacity or ANC in short is a measure for the overall buffering capacity against acidification of a solution, e.g. surface water or soil water.. ANC is defined as the difference between cations of strong bases and anions of strong acids (see below), or dynamically as the amount of acid needed to change the pH value from the sample's value to a chosen different value. [1]
The ocean contains a natural buffer system to maintain a pH between 8.1 and 8.3. [11] The oceans buffer system is known as the carbonate buffer system. [ 12 ] The carbonate buffer system is a series of reactions that uses carbonate as a buffer to convert C O 2 {\displaystyle \mathrm {CO_{2}} } into bicarbonate . [ 12 ]
Phenolphthalein's pH sensitivity is exploited in other applications: concrete has naturally high pH due to the calcium hydroxide formed when Portland cement reacts with water. As the concrete reacts with carbon dioxide in the atmosphere, pH decreases to 8.5–9. When a 1% phenolphthalein solution is applied to normal concrete, it turns bright pink.
The flow table test or slump-flow test is a method to determine consistency of fresh concrete. Flow table test is also used to identify transportable moisture limit of solid bulk cargoes. [ 1 ] It is used primarily for assessing concrete that is too fluid (workable) to be measured using the slump test , because the concrete will not retain its ...
The test is carried out using a metal mould in the shape of a conical frustum known as a slump cone or Abrams cone, that is open at both ends and has attached handles.The tool typically has an internal diameter of 100 millimetres (3.9 in) at the top and of 200 millimetres (7.9 in) at the bottom with a height of 305 millimetres (12.0 in).The cone is placed on a hard non-absorbent surface.
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