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2-Hexyne can be semihydrogenated to yield 2-hexene or fully hydrogenated to hexane. [3] With appropriate noble metal catalysts it can selectively form cis-2-hexene. [4] 2-Hexyne can act as a ligand on gold atoms. [5] With strong sulfuric acid, the ketone 2-hexanone is produced. However this reaction also causes polymerization and charring. [6]
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The hexynes are a subgroup from the group of alkynes.It consists of several isomeric compounds having the formula C 6 H 10.. The linear and branched members are: 1-Hexyne (n-butylacetylene)
3-Hexyne is the organic compound with the formula C 2 H 5 CCC 2 H 5. This colorless liquid is one of three isomeric hexynes. 3-Hexyne forms with 5-decyne, 4-octyne, and 2-butyne a series of symmetric alkynes. It is a reagent in organometallic chemistry. [1] Structure of the coordination complex NbCl 3 (dimethoxyethane)(3-hexyne). [2]
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1-Hexyne can be prepared by the reaction of monosodium acetylide with butyl bromide: [1] NaC 2 H + BrC 4 H 9 → HC 2 C 4 H 9 + NaBr. Its reactivity illustrates the behavior of terminal alkylacetylenes. The hexyl derivative is common test substrate because it is conveniently volatile. It undergoes deprotonation at C-3 and C-1 with butyl lithium: