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A representative pressure–volume diagram for a refrigeration cycle. Vapour-compression refrigeration or vapor-compression refrigeration system (VCRS), [1] in which the refrigerant undergoes phase changes, is one of the many refrigeration cycles and is the most widely used method for air conditioning of buildings and automobiles.
Common absorption refrigerators use a refrigerant with a very low boiling point (less than −18 °C (0 °F)) just like compressor refrigerators.Compression refrigerators typically use an HCFC or HFC, while absorption refrigerators typically use ammonia or water and need at least a second fluid able to absorb the coolant, the absorbent, respectively water (for ammonia) or brine (for water).
Anhydrous ammonia is widely used in industrial refrigeration applications and hockey rinks because of its high energy efficiency and low cost. R-1234yf HFO-1234yf: C 3 H 2 F 4: 2,3,3,3-Tetrafluoropropene <1: Less performance but also less flammable than R-290. [57]
Ammonia forms 1:1 adducts with a variety of Lewis acids such as I 2, phenol, and Al(CH 3) 3. Ammonia is a hard base (HSAB theory) and its E & C parameters are E B = 2.31 and C B = 2.04. Its relative donor strength toward a series of acids, versus other Lewis bases, can be illustrated by C-B plots.
Commercial refrigeration. Refrigeration is any of various types of cooling of a space, substance, or system to lower and/or maintain its temperature below the ambient one (while the removed heat is ejected to a place of higher temperature). [1] [2] Refrigeration is an artificial, or human-made, cooling method. [1] [2]
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A Crosley IcyBall with cold side ball on left, hot side ball on right. Icyball is a name given to two early refrigerators, one made by Australian Sir Edward Hallstrom in 1923, and the other design patented by David Forbes Keith of Toronto (filed 1927, granted 1929), [1] [2] and manufactured by American Powel Crosley Jr., who bought the rights to the device.
For instance, in a refrigeration unit, the working fluid is called the refrigerant. Ammonia is a typical refrigerant and may be used as the primary working fluid. Compared with water (which can also be used as a refrigerant), ammonia makes use of relatively high pressures requiring more robust and expensive equipment.