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Electron affinity can be defined in two equivalent ways. First, as the energy that is released by adding an electron to an isolated gaseous atom. The second (reverse) definition is that electron affinity is the energy required to remove an electron from a singly charged gaseous negative ion.
The electron affinity of molecules is a complicated function of their electronic structure. For instance the electron affinity for benzene is negative, as is that of naphthalene, while those of anthracene, phenanthrene and pyrene are positive. In silico experiments show that the electron affinity of hexacyanobenzene surpasses that of fullerene. [5]
It is also referred to as ionization potential. The first ionization energy is the amount of energy that is required to remove the first electron from a neutral atom. The energy needed to remove the second electron from the neutral atom is called the second ionization energy and so on. [10] [11] [12]
The first electron affinity of chlorine (the energy release when chlorine gains an electron to form Cl −) is 349 kJ per mole of chlorine atoms. [1] Adding a second electron to form a hypothetical Cl 2- would require energy, energy that cannot be recovered by the formation of a chemical bond.
The first of these quantities is used in atomic physics, the second in chemistry, but both refer to the same basic property of the element. To convert from "value of ionization energy" to the corresponding "value of molar ionization energy", the conversion is: 1 eV = 96.48534 kJ/mol 1 kJ/mol = 0.0103642688 eV [12]
The energy required to remove one or more electrons to make a cation is a sum of successive ionization energies; for example, the energy needed to form Mg 2+ is the ionization energy required to remove the first electron from Mg, plus the ionization energy required to remove the second electron from Mg +. Electron affinity is defined as the ...
This is an accepted version of this page This is the latest accepted revision, reviewed on 17 November 2024. Development of the table of chemical elements The American chemist Glenn T. Seaborg —after whom the element seaborgium is named—standing in front of a periodic table, May 19, 1950 Part of a series on the Periodic table Periodic table forms 18-column 32-column Alternative and ...
Chlorine (symbol Cl) is the second-lightest halogen. The element forms diatomic molecules under standard conditions, called dichlorine. It has the highest electron affinity and the one of highest electronegativity of all the elements; thus chlorine is a strong oxidizing agent.