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In physics, the Young–Laplace equation (/ l ə ˈ p l ɑː s /) is an algebraic equation that describes the capillary pressure difference sustained across the interface between two static fluids, such as water and air, due to the phenomenon of surface tension or wall tension, although use of the latter is only applicable if assuming that the wall is very thin.
A century later Gibbs [3] proposed a modification to Young's equation to account for the volumetric dependence of the contact angle. Gibbs postulated the existence of a line tension, which acts at the three-phase boundary and accounts for the excess energy at the confluence of the solid-liquid-gas phase interface, and is given as:
Surface tension is an important factor in the phenomenon of capillarity. Surface tension has the dimension of force per unit length, or of energy per unit area. [4] The two are equivalent, but when referring to energy per unit of area, it is common to use the term surface energy, which is a more general term in the sense that it applies also to ...
Flux F through a surface, dS is the differential vector area element, n is the unit normal to the surface. Left: No flux passes in the surface, the maximum amount flows normal to the surface. Right: The reduction in flux passing through a surface can be visualized by reduction in F or dS equivalently (resolved into components, θ is angle to ...
which relates the surface tensions between the three phases: solid, liquid and gas. Subsequently, this predicts the contact angle of a liquid droplet on a solid surface from knowledge of the three surface energies involved. This equation also applies if the "gas" phase is another liquid, immiscible with the droplet of the first "liquid" phase.
LEP depends on many parameters, including the membrane maximum pore size, the surface tension of the liquid, the contact angle of the liquid on the membrane surface, and the geometrical structure of the membrane. [1] In the simplest form based on the Young–Laplace equation, [2] the LEP is specified as:
Surface tension – Tendency of a liquid surface to shrink to reduce surface area; Tribology – Science and engineering of interacting surfaces in relative motion; Unilateral contact – Mechanical constraint which prevents penetration between two bodies; Wetting – Ability of a liquid to maintain contact with a solid surface
A: The bottom of a concave meniscus. B: The top of a convex meniscus. In physics (particularly fluid statics), the meniscus (pl.: menisci, from Greek 'crescent') is the curve in the upper surface of a liquid close to the surface of the container or another object, produced by surface tension.