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904L is an austenitic stainless steel.It is softer than 316L, [1] [2] and its molybdenum addition gives it superior resistance to localized attack (pitting and crevice corrosion) by chlorides and greater resistance reducing acids; in particular, its copper addition gives it useful corrosion resistance to all concentrations of sulfuric acid.
Strong acids, such as hydrochloric acid and sulfuric acid are common, but different applications use various other acids. Also alkaline solutions can be used for cleaning metal surfaces. Solutions usually also contain additives such as wetting agents and corrosion inhibitors. Pickling is sometimes called acid cleaning if descaling is not needed ...
A typical mixture is 3 parts of concentrated sulfuric acid and 1 part of 30 wt. % hydrogen peroxide solution; [1] other protocols may use a 4:1 or even 7:1 mixture. A closely related mixture, sometimes called "base piranha", is a 5:1:1 mixture of water, ammonia solution ( NH 4 OH , or NH 3 (aq) ), and 30% hydrogen peroxide.
Conversion and its related terms yield and selectivity are important terms in chemical reaction engineering.They are described as ratios of how much of a reactant has reacted (X — conversion, normally between zero and one), how much of a desired product was formed (Y — yield, normally also between zero and one) and how much desired product was formed in ratio to the undesired product(s) (S ...
Sulfuric acid is one of the most-produced industrial chemicals. At room temperature, type 304 stainless steel is only resistant to 3% acid, while type 316 is resistant to 3% acid up to 50 °C (120 °F) and 20% acid at room temperature. Thus type 304 SS is rarely used in contact with sulfuric acid.
Electrolytes used for electropolishing are most often concentrated acid solutions such as mixtures of sulfuric acid and phosphoric acid. Other electropolishing electrolytes reported in the literature include mixtures of perchloric acid with acetic anhydride (which has caused fatal explosions), and methanolic solutions of sulfuric acid. [3]
Alloy 20 (Carpenter 20) is an austenitic stainless steel possessing excellent resistance to hot sulfuric acid and many other aggressive environments which would readily attack type 316 stainless. This alloy exhibits superior resistance to stress-corrosion cracking in boiling 20–40% sulfuric acid.
SAE 316L grade stainless steel, sometimes referred to as A4 stainless steel or marine grade stainless steel, is the second most common austenitic stainless steel after 304/A2 stainless steel. Its primary alloying constituents after iron , are chromium (between 16–18%), nickel (10–12%) and molybdenum (2–3%), up to 2% manganese , [ 1 ] with ...