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In physics, the thermal equation of state is a mathematical expression of pressure P, temperature T, and, volume V.The thermal equation of state for ideal gases is the ideal gas law, expressed as PV=nRT (where R is the gas constant and n the amount of substance), while the thermal equation of state for solids is expressed as:
A vapor can exist in equilibrium with a liquid (or solid), in which case the gas pressure equals the vapor pressure of the liquid (or solid). A supercritical fluid (SCF) is a gas whose temperature and pressure are above the critical temperature and critical pressure respectively. In this state, the distinction between liquid and gas disappears.
The various solid/liquid/gas transitions are classified as first-order transitions because they involve a discontinuous change in density, which is the (inverse of the) first derivative of the free energy with respect to pressure.
At standard temperature and pressure, it forms a monatomic gas with a density of 9.73 kg/m 3, about 8 times the density of the Earth's atmosphere at sea level, 1.217 kg/m 3. [16] It is one of the densest gases at room temperature (a few are denser, e.g. CF 3 (CF 2 ) 2 CF 3 and WF 6 ) and is the densest of the noble gases.
The density of propane gas at 25 °C (77 °F) is 1.808 kg/m 3, about 1.5× the density of air at the same temperature. The density of liquid propane at 25 °C (77 °F) is 0.493 g/cm 3, which is equivalent to 4.11 pounds per U.S. liquid gallon or 493 g/L. Propane expands at 1.5% per 10 °F. Thus, liquid propane has a density of approximately 4.2 ...
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
Real fluids at low density and high temperature approximate the behavior of a classical ideal gas. However, at lower temperatures or a higher density, a real fluid deviates strongly from the behavior of an ideal gas, particularly as it condenses from a gas into a liquid or as it deposits from a gas into a solid.
The density of butane is highly dependent on temperature and pressure in the reservoir. [19] For example, the density of liquid butane is 571.8±1 kg/m 3 (for pressures up to 2 MPa and temperature 27±0.2 °C), while the density of liquid butane is 625.5±0.7 kg/m 3 (for pressures up to 2 MPa and temperature −13±0.2 °C).