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The second law of thermodynamics may be expressed in many specific ways, [23] the most prominent classical statements [24] being the statement by Rudolf Clausius (1854), the statement by Lord Kelvin (1851), and the statement in axiomatic thermodynamics by Constantin Carathéodory (1909). These statements cast the law in general physical terms ...
[1] [2] [3] A more fundamental statement was later labelled as the zeroth law after the first three laws had been established. The zeroth law of thermodynamics defines thermal equilibrium and forms a basis for the definition of temperature: if two systems are each in thermal equilibrium with a third system, then they are in thermal equilibrium ...
kelvin: K thermodynamic temperature "The kelvin, symbol K, is the SI unit of thermodynamic temperature. It is defined by taking the fixed numerical value of the Boltzmann constant k to be 1.380 649 × 10 −23 when expressed in the unit J K −1, which is equal to kg m 2 s −2 K −1, where the kilogram, metre and second are defined in terms ...
Black-body radiation has a characteristic, continuous frequency spectrum that depends only on the body's temperature, [8] called the Planck spectrum or Planck's law. The spectrum is peaked at a characteristic frequency that shifts to higher frequencies with increasing temperature, and at room temperature most of the emission is in the infrared ...
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The Planck statement applies only to perfect crystalline substances: As temperature falls to zero, the entropy of any pure crystalline substance tends to a universal constant. That is, lim T → 0 S = S 0 {\displaystyle \lim _{T\to 0}S=S_{0}} , where S 0 {\displaystyle S_{0}} is a universal constant that applies for all possible crystals, of ...
To make it into a dimensionless quantity, we must divide it by h, which is some quantity with units of action (usually taken to be the Planck constant). Classical continuous system (multiple identical particles)
Thermodynamic temperature is a quantity defined in thermodynamics as distinct from kinetic theory or statistical mechanics.. Historically, thermodynamic temperature was defined by Lord Kelvin in terms of a macroscopic relation between thermodynamic work and heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are ...