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Biogenic sulfide corrosion is a bacterially mediated process of forming hydrogen sulfide gas and the subsequent conversion to sulfuric acid that attacks concrete and steel within wastewater environments. The hydrogen sulfide gas is biochemically oxidized in the presence of moisture to form sulfuric acid.
Sediment samples to be analyzed are first purged with argon or nitrogen gas to ensure they are anoxic. The sample is placed in a flask connected to an apparatus for trapping hydrogen sulfide gas (H 2 S). Oxygen-free water and hydrochloric acid (HCl) are added, and the sediment is stirred for one hour while argon or nitrogen gas is bubbled ...
A number of processes have been designed to remove hydrogen sulfide from drinking water. [54] Continuous chlorination For levels up to 75 mg/L chlorine is used in the purification process as an oxidizing chemical to react with hydrogen sulfide. This reaction yields insoluble solid sulfur. Usually the chlorine used is in the form of sodium ...
The by-product gases mainly originate from physical and chemical gas treatment units (Selexol, Rectisol, Purisol and amine scrubbers) in refineries, natural gas processing plants and gasification or synthesis gas plants. These by-product gases may also contain hydrogen cyanide, hydrocarbons, sulfur dioxide or ammonia.
The residual hydrogen, methane, ethane, and some propane is used as refinery fuel gas. The hydrogen sulfide removed and recovered by the amine gas treating unit is subsequently converted to elemental sulfur in a Claus process unit or to sulfuric acid in a wet sulfuric acid process or in the conventional Contact Process.
Sulfate-reducing microorganisms are responsible for the sulfurous odors of salt marshes and mud flats. Much of the hydrogen sulfide will react with metal ions in the water to produce metal sulfides. These metal sulfides, such as ferrous sulfide (FeS), are insoluble and often black or brown, leading to the dark color of sludge. [2]
The deuterium in the hot loop slightly prefers to be in the hydrogen sulfide, resulting in excess deuterium in the hydrogen sulfide relative to the cold tower. For n moles of deuterium per mole of protium in the hot tower input water, there are n / 1.82 moles per mole of protium in the hydrogen sulfide. In the cold tower, part of this ...
The hydrogen cycle consists of hydrogen exchanges between biotic (living) and abiotic (non-living) sources and sinks of hydrogen-containing compounds. Hydrogen (H) is the most abundant element in the universe. [1] On Earth, common H-containing inorganic molecules include water (H 2 O), hydrogen gas (H 2), hydrogen sulfide (H 2 S), and ammonia ...