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In physics, Hooke's law is an empirical law which states that the force (F) needed to extend or compress a spring by some distance (x) scales linearly with respect to that distance—that is, F s = kx, where k is a constant factor characteristic of the spring (i.e., its stiffness), and x is small compared to the total possible deformation of the spring.
Thermodynamic work is one of the principal kinds of process by which a thermodynamic system can interact with and transfer energy to its surroundings. This results in externally measurable macroscopic forces on the system's surroundings, which can cause mechanical work, to lift a weight, for example, [1] or cause changes in electromagnetic, [2] [3] [4] or gravitational [5] variables.
For a stretched spring fixed at one end obeying Hooke's law, the elastic potential energy is Δ E p = 1 2 k ( r 2 − r 1 ) 2 {\displaystyle \Delta E_{p}={\frac {1}{2}}k(r_{2}-r_{1})^{2}} where r 2 and r 1 are collinear coordinates of the free end of the spring, in the direction of the extension/compression, and k is the spring constant.
For example, when a person pushes a heavy box a few metres forward, that person exerts mechanical energy, also known as work, on the box over a distance of a few meters forward. The mathematical definition of this form of energy is the product of the force exerted on the object and the distance by which the box moved ( Work = Force × Distance ).
Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the ...
The law states that the total enthalpy change during the complete course of a chemical reaction is independent of the sequence of steps taken. [2] [3] Hess's law is now understood as an expression of the fact that the enthalpy of a chemical process is independent of the path taken from the initial to the final state (i.e. enthalpy is a state ...
In orthogonal coordinates, the elastic energy per unit volume due to strain is thus a sum of contributions: =, where is a 4th rank tensor, called the elastic tensor or stiffness tensor [3] which is a generalization of the elastic moduli of mechanical systems, and is the strain tensor (Einstein summation notation has been used to imply summation ...
The first and second law of thermodynamics are the most fundamental equations of thermodynamics. They may be combined into what is known as fundamental thermodynamic relation which describes all of the changes of thermodynamic state functions of a system of uniform temperature and pressure.
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