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Permeability is typically determined in the lab by application of Darcy's law under steady state conditions or, more generally, by application of various solutions to the diffusion equation for unsteady flow conditions. [8] Permeability needs to be measured, either directly (using Darcy's law), or through estimation using empirically derived ...
Knudsen diffusion, named after Martin Knudsen, is a means of diffusion that occurs when the scale length of a system is comparable to or smaller than the mean free path of the particles involved. An example of this is in a long pore with a narrow diameter (2–50 nm) because molecules frequently collide with the pore wall. [ 1 ]
The Knudsen number is a dimensionless number defined as =, where = mean free path [L 1], = representative physical length scale [L 1].. The representative length scale considered, , may correspond to various physical traits of a system, but most commonly relates to a gap length over which thermal transport or mass transport occurs through a gas phase.
A more accurate correction factor can be obtained using Knudsen correction. When using nitrogen gas for core plug measurements, the Klinkenberg correction is usually necessary due to the so-called Klinkenberg gas slippage effect. This takes place when the pore space approaches the mean free path of the gas
Permeability is affected by the penetrant size. Larger gas molecules have a lower diffusion coefficient. The polymer chain flexibility and free volume in the polymer of the membrane material influence the diffusion coefficient, as the space within the permeable membrane must be large enough for the gas molecules to diffuse across.
Knudsen flow describes the movement of fluids with a Knudsen number near unity, that is, where the characteristic length in the flow space is of the same order of magnitude as the mean free path. Depending on the source there is a range mentioned of 0.1<Kn<10 for which Knudsen flow occurs.
In fluid dynamics, the Knudsen equation is used to describe how gas flows through a tube in free molecular flow. When the mean free path of the molecules in the gas is larger than or equal to the diameter of the tube, the molecules will interact more often with the walls of the tube than with each other. For typical tube dimensions, this occurs ...
By expanding the particle distribution function into equilibrium and non-equilibrium components and using the Chapman-Enskog expansion, where is the Knudsen number, the Taylor-expanded LBE can be decomposed into different magnitudes of order for the Knudsen number in order to obtain the proper continuum equations: