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Lead perchlorate trihydrate is produced by the reaction of lead(II) oxide, lead carbonate, or lead nitrate by perchloric acid: . Pb(NO 3) 2 + HClO 4 → Pb(ClO 4) 2 + HNO 3. The excess perchloric acid was removed by first heating the solution to 125 °C, then heating it under moist air at 160 °C to remove the perchloric acid by converting the acid to the dihydrate.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
2 PbCl 2 + 4 RMgBr → R 4 Pb + Pb + 4 MgBrCl 3 PbCl 2 + 6 RMgBr → R 3 Pb-PbR 3 + Pb + 6 MgBrCl [12] These reactions produce derivatives that are more similar to organosilicon compounds, i.e. that Pb(II) tends to disproportionate upon alkylation. PbCl 2 can be used to produce PbO 2 by treating it with sodium hypochlorite (NaClO), forming a ...
It dissolves in nitric acid with the evolution of nitric oxide gas to form dissolved Pb(NO 3) 2. 3 Pb + 8 H + + 8 NO − 3 → 3 Pb 2+ + 6 NO − 3 + 2 NO + 4 H 2 O. When heated with nitrates of alkali metals, metallic lead oxidizes to form PbO (also known as litharge), leaving the corresponding alkali nitrite. PbO is representative of lead's ...
Cotunnite is the natural mineral form of lead(II) chloride (PbCl 2). Unlike the pure compound, which is white, cotunnite can be white, yellow, or green. The density of mineral samples spans range 5.3–5.8 g/cm 3. The hardness on the Mohs scale is 1.5–2. The crystal structure is orthorhombic dipyramidal and the point group is 2/m 2/m 2/m.
Chlorate is the common name of the ClO − 3 anion, whose chlorine atom is in the +5 oxidation state.The term can also refer to chemical compounds containing this anion, with chlorates being the salts of chloric acid.
Lead(II) acetate is a white crystalline chemical compound with a slightly sweet taste. Its chemical formula is usually expressed as Pb(CH 3 COO) 2 or Pb(OAc) 2, where Ac represents the acetyl group. Like many other lead compounds, it causes lead poisoning. Lead acetate is soluble in water and glycerin.
Thus while carbon tetrachloride is a stable compound, with lead the oxidation state +2 is favored and PbCl 4 quickly becomes PbCl 2. Indeed, the inert pair effect causes lead to favor its +2 oxidation state: Pb atom loses all its outermost p electrons and ends up with a stable, filled s subshell. [7]