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Overall, decarboxylation depends upon stability of the carbanion synthon R − , [ 1 ] [ 2 ] although the anion may not be a true chemical intermediate . [ 3 ] [ 4 ] Typically, carboxylic acids decarboxylate slowly, but carboxylic acids with an α electron-withdrawing group (e.g. β‑ keto acids , β‑nitriles, α‑ nitro acids, or ...
Calvin–Benson cycle. C 3 carbon fixation is the most common of three metabolic pathways for carbon fixation in photosynthesis, the other two being C 4 and CAM.This process converts carbon dioxide and ribulose bisphosphate (RuBP, a 5-carbon sugar) into two molecules of 3-phosphoglycerate through the following reaction:
The main carboxylating enzyme in C 3 photosynthesis is called RuBisCO, which catalyses two distinct reactions using either CO 2 (carboxylation) or oxygen (oxygenation) as a substrate. RuBisCO oxygenation gives rise to phosphoglycolate, which is toxic and requires the expenditure of energy to recycle through photorespiration.
The following is a breakdown of the energetics of the photosynthesis process from Photosynthesis by Hall and Rao: [6]. Starting with the solar spectrum falling on a leaf, 47% lost due to photons outside the 400–700 nm active range (chlorophyll uses photons between 400 and 700 nm, extracting the energy of one 700 nm photon from each one)
Cyanobacteria such as these carry out photosynthesis. Their emergence foreshadowed the evolution of many photosynthetic plants and oxygenated Earth's atmosphere. Biological carbon fixation, or сarbon assimilation, is the process by which living organisms convert inorganic carbon (particularly carbon dioxide) to organic compounds.
A carbocation is an ion with a positively charged carbon atom. Among the simplest examples are the methenium CH + 3, methanium CH + 5, acylium ions RCO +, and vinyl C ...
To do this, it must release the absorbed energy. This can happen in various ways. The extra energy can be converted into molecular motion and lost as heat, or re-emitted by the electron as light (fluorescence). The energy, but not the electron itself, may be passed onto another molecule; this is called resonance energy transfer.
Other studies on the stability of the 2-norbornyl cation have shown that the alkyl substitutions at carbon 1 or 2 force the system to be decidedly classical. Tertiary carbocations are much more stable than their secondary counterparts and therefore do not need to adopt delocalized bonding in order to reach the lowest possible potential energy.
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