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The molar ionic strength, I, of a solution is a function of the concentration of all ions present in that solution. [3]= = where one half is because we are including both cations and anions, c i is the molar concentration of ion i (M, mol/L), z i is the charge number of that ion, and the sum is taken over all ions in the solution.
Atomic numbers (Z) are a special case of charge numbers, referring to the charge number of an atomic nucleus, as opposed to the net charge of an atom or ion. The charge numbers for ions (and also subatomic particles ) are written in superscript, e.g., Na + is a sodium ion with charge number positive one (an electric charge of one elementary ...
When charged particles move in electric and magnetic fields the following two laws apply: Lorentz force law: = (+),; Newton's second law of motion: = =; where F is the force applied to the ion, m is the mass of the particle, a is the acceleration, Q is the electric charge, E is the electric field, and v × B is the cross product of the ion's velocity and the magnetic flux density.
The electrical charge of the Na + and Cl − ion are assumed to be onefold positive and negative, respectively, z Na = 1 and z Cl = –1. The nearest neighbour distance amounts to half the lattice constant of the cubic unit cell r 0 = a 2 {\displaystyle r_{0}={\tfrac {a}{2}}} and the Madelung constants become
Ionic potential is the ratio of the electrical charge (z) to the radius (r) of an ion. [1]= = As such, this ratio is a measure of the charge density at the surface of the ion; usually the denser the charge, the stronger the bond formed by the ion with ions of opposite charge.
There are additional names used for ions with multiple charges. For example, an ion with a −2 charge is known as a dianion and an ion with a +2 charge is known as a dication. A zwitterion is a neutral molecule with positive and negative charges at different locations within that molecule. [17]
The electrostatic potential energy, E pair, between a pair of ions of equal and opposite charge is: = where z = magnitude of charge on one ion e = elementary charge, 1.6022 × 10 −19 C ε 0 = permittivity of free space 4 π ε 0 = 1.112 × 10 −10 C 2 /(J·m)
Formal charges in ozone and the nitrate anion. In chemistry, a formal charge (F.C. or q*), in the covalent view of chemical bonding, is the hypothetical charge assigned to an atom in a molecule, assuming that electrons in all chemical bonds are shared equally between atoms, regardless of relative electronegativity.