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[note 1] [74] [75] [76] Caesium was the first element to be discovered with a spectroscope, which had been invented by Bunsen and Kirchhoff only a year previously. [ 17 ] To obtain a pure sample of caesium, 44,000 litres (9,700 imp gal; 12,000 US gal) of mineral water had to be evaporated to yield 240 kilograms (530 lb) of concentrated salt ...
Robert Wilhelm Eberhard Bunsen (German:; 30 March 1811 [a] – 16 August 1899) was a German chemist. He investigated emission spectra of heated elements, and discovered caesium (in 1860) and rubidium (in 1861) with the physicist Gustav Kirchhoff. [11] The Bunsen–Kirchhoff Award for spectroscopy is named after Bunsen and Kirchhoff.
Spectroscope of Kirchhoff and Bunsen. The systematic attribution of spectra to chemical elements began in the 1860s with the work of German physicists Robert Bunsen and Gustav Kirchhoff, [30] who found that Fraunhofer lines correspond to emission spectral lines observed in laboratory light sources. This laid way for spectrochemical analysis in ...
In 1860, the unexpected appearance of sky-blue and dark red was observed in spectral emissions by Robert Bunsen and Gustav Kirchhoff, leading to the discovery of two alkali metals, caesium and rubidium (dark red). [4] [1] Today, this low-cost method is used in secondary education to teach students to detect metals in samples qualitatively. [2]
It is the least electronegative element with stable isotopes, of which it has only one, caesium-133. Caesium is mined mostly from pollucite, while the radioisotopes, especially caesium-137, are extracted from waste produced by nuclear reactors. German chemists Robert Bunsen and Gustav Kirchhoff discovered caesium in 1860 by flame spectroscopy.
They discovered caesium by its two blue emission lines in a sample of Dürkheim mineral water. [130] The pure metal was eventually isolated in 1882 by Setterberg. [131] 37 Rubidium: 1861 R. Bunsen and G. R. Kirchhoff: 1863 R. Bunsen Bunsen and Kirchhoff discovered it just a few months after caesium, by observing new spectral lines in the ...
Kirchhoff and Bunsen discovered caesium and rubidium in 1861. In 1866, Christomanos brought the spectroscope to Greece and used the instrument on the island of Santorini to research the volcanic eruption of the Santorini caldera in 1866.
[39] [40] Rubidium was the second element, shortly after caesium, to be discovered by spectroscopy, just one year after the invention of the spectroscope by Bunsen and Kirchhoff. [41] The two scientists used the rubidium chloride to estimate that the atomic weight of the new element was 85.36 (the currently accepted value is 85.47). [39]