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Standard enthalpy of neutralization is the change in enthalpy that occurs when an acid and base undergo a neutralization reaction to form one mole of water. For example in aqueous solution, the standard enthalpy of neutralization of hydrochloric acid and the base magnesium hydroxide refers to the reaction HCl (aq) + 1/2 Mg(OH) 2 → 1/2 MgCl 2 ...
The bond dissociation energy (enthalpy) [4] is also referred to as bond disruption energy, bond energy, bond strength, or binding energy (abbreviation: BDE, BE, or D). It is defined as the standard enthalpy change of the following fission: R—X → R + X. The BDE, denoted by Dº(R—X), is usually derived by the thermochemical equation,
B(F–F), the standard enthalpy of atomization (or bond energy) of fluorine gas. EA F, the electron affinity of a fluorine atom. U L, the lattice energy of lithium fluoride. The sum of these enthalpies give the standard enthalpy of formation (Δ f H) of lithium fluoride:
The term bond-dissociation energy is similar to the related notion of bond-dissociation enthalpy (or bond enthalpy), which is sometimes used interchangeably.However, some authors make the distinction that the bond-dissociation energy (D 0) refers to the enthalpy change at 0 K, while the term bond-dissociation enthalpy is used for the enthalpy change at 298 K (unambiguously denoted DH° 298).
Thermodynamic databases contain information about thermodynamic properties for substances, the most important being enthalpy, entropy, and Gibbs free energy.Numerical values of these thermodynamic properties are collected as tables or are calculated from thermodynamic datafiles.
Std enthalpy change of fusion, Δ fus H o +5.653 kJ/mol Std entropy change of fusion, Δ fus S o +28.93 J/(mol·K) Std enthalpy change of vaporization, Δ vap H o +23.35 kJ/mol at BP of −33.4 °C Std entropy change of vaporization, Δ vap S o +97.41 J/(mol·K) at BP of −33.4 °C Solid properties Std enthalpy change of formation, Δ f H o ...
Std enthalpy change of formation Δ f H o liquid: −483.5 kJ/mol Standard molar entropy S o liquid: 158.0 J/(mol K) Enthalpy of combustion, Δ c H o –876.1 kJ/mol Heat capacity c p: 123.1 J/(mol K) Gas properties Std enthalpy change of formation Δ f H o gas –438.1 kJ/mol Standard molar entropy S o gas: 282.84 J/(mol K) Heat capacity c p ...
Std enthalpy change of formation, Δ f H o liquid –134.3 kJ/mol Standard molar entropy, S o liquid? J/(mol K) Enthalpy of combustion –473.2 kJ/mol Δ c H o: Heat capacity, c p: 114.25 J/(mol K) Gas properties Std enthalpy change of formation, Δ f H o gas –103.18 kJ/mol Standard molar entropy, S o gas: 295.6 J/(mol K) at 25 °C Heat ...