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PbCl 2 is used in synthesis of lead(IV) chloride (PbCl 4): Cl 2 is bubbled through a saturated solution of PbCl 2 in aqueous NH 4 Cl forming [NH 4] 2 [PbCl 6]. The latter is reacted with cold concentrated sulfuric acid (H 2 SO 4) forming PbCl 4 as an oil. [10] Lead(II) chloride is the main precursor for organometallic derivatives of lead, such ...
Lead readily forms an equimolar alloy with sodium metal that reacts with alkyl halides to form organometallic compounds of lead such as tetraethyllead. [15] The Pb–C bond energies in TML and TEL are only 167 and 145 kJ/mol; the compounds thus decompose upon heating, with first signs of TEL composition seen at 100 °C (210 °F).
Organolead compounds can be derived from Grignard reagents and lead chloride. For example, methylmagnesium chloride reacts with lead chloride to tetramethyllead, a water-clear liquid with boiling point 110 °C and density 1.995 g/cm 3. Reaction of a lead(II) source with sodium cyclopentadienide gives the lead metallocene, plumbocene.
Organ pipes are often made from a lead alloy, mixed with various amounts of tin to control the tone of each pipe. [231] [232] Lead is an established shielding material from radiation in nuclear science and in X-ray rooms [233] due to its denseness and high attenuation coefficient. [234] Molten lead has been used as a coolant for lead-cooled ...
Phase behavior Triple point? K (? °C), ? Pa Critical point? K (? °C), ? Pa Std enthalpy change of fusion, Δ fus H o? kJ/mol Std entropy change of fusion, Δ fus S oJ/(mol·K)
Lead chloride may refer to: Lead(II) chloride (plumbous chloride), mineral name: cotunnite. Lead(IV) chloride (plumbic chloride) Hexachloroplumbate(IV) (dianion)
The House erupted into applause when the House announced former Rep. Matt Gaetz would officially be stepping down from his Florida seat and would no longer be a member of the 119th Congress.
The composition of fluxes is tailored for the required properties - the base metals and their surface preparation (which determine the composition and thickness of surface oxides), the solder (which determines the wetting properties and the soldering temperature), the corrosion resistance and ease of removal, and others.