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Partition coefficient (K D) - The ratio of concentrations of a compound in two phases of a mixture of two immiscible solvents at equilibrium. Hall coefficient (electrical physics) - Relates a magnetic field applied to an element to the voltage created, the amount of current and the element thickness. It is a characteristic of the material from ...
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...
A constant coefficient, also known as constant term or simply constant, is a quantity either implicitly attached to the zeroth power of a variable or not attached to other variables in an expression; for example, the constant coefficients of the expressions above are the number 3 and the parameter c, involved in 3=c ⋅ x 0.
The partition coefficient generally refers to the concentration ratio of un-ionized species of compound, whereas the distribution coefficient refers to the concentration ratio of all species of the compound (ionized plus un-ionized). [1] In the chemical and pharmaceutical sciences, both phases usually are solvents. [2]
In thermodynamics, an activity coefficient is a factor used to account for deviation of a mixture of chemical substances from ideal behaviour. [1] In an ideal mixture, the microscopic interactions between each pair of chemical species are the same (or macroscopically equivalent, the enthalpy change of solution and volume variation in mixing is zero) and, as a result, properties of the mixtures ...
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
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Charge transfer coefficient, and symmetry factor (symbols α and β, respectively) are two related parameters used in description of the kinetics of electrochemical reactions. They appear in the Butler–Volmer equation and related expressions.