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Fluorobenzaldehyde can be used as a synthetic intermediate because the fluorine can be replaced via oxidation reaction. [1] Due to the aldehyde group, the fluorobenzaldehydes can be used to make a variety of schiff base compounds through a condensation reaction, some of which have antimicrobial properties. [2] [3]
4-Chlorobenzaldehyde (o-Chlorobenzaldehyde) is an organic compound with the formula ClC 5 H 4 CHO. It is one of three isomeric monochlorinated benzaldehydes . Preparation
PhN=N-N(CH 2) 5 + 2 HF → PhF + N 2 + [(CH 2) 5 NH 2]F. Historical note: in Wallach's era, the element fluorine was symbolized with "Fl". Thus, his procedure is subtitled "Fluorbenzol, C 6 H 5 Fl". [1] On the laboratory scale, PhF is prepared by the thermal decomposition of the benzenediazonium tetrafluoroborate: PhN 2 BF 4 → PhF + BF 3 + N 2
2-Chlorobenzaldehyde (o-chlorobenzaldehyde) is an organic compound with the formula ClC 5 H 4 CHO. It is one of three isomeric monochlorinated benzaldehyde. 3-Chlorobenzaldehyde and 4-chlorobenzaldehyde are the other isomers. Whereas benzaldehyde is prone to autoxidation, the 2-chloro derivatives are more air-stable.
2-Chloro-6-fluorobenzaldehyde is prepared by oxidation of 2-chloro-6-fluorotolulene by chromyl chloride. [3] It reacts with sodium hydroxide to give a mixture of 2-chloro-6-fluorobenzene and 6-chlorosalicaldehyde. [4] 2-Chloro-6-fluorobenzaldehyde is used in the production of the antiseptics dicloxacillin and flucloxacillin.
CFT is used to prepare 2-chloro-6-fluorobenzaldehyde via oxidation with hydrogen peroxide, which forms an aldehyde group. [ 2 ] CFT is also used in the preparation of 4-chloro-1 H -indazole .
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Many organochlorine compounds have been isolated from natural sources ranging from bacteria to humans. [2] [3] Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids.
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