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syn/anti peri/clinal. a torsion angle between 0° and ±90° is called syn (s) a torsion angle between ±90° and 180° is called anti (a) a torsion angle between 30° and 150° or between −30° and −150° is called clinal (c) a torsion angle between 0° and ±30° or ±150° and 180° is called periplanar (p)
The use of syn and anti to indicate the configuration of double bonds is nowadays obsolete, especially in case of aldoximes and hydrazones derived from aldehydes. Here, the compounds were designated as syn configured when the aldehyde H and the O (of the oxime) or the N (of the hydrazone) were cis aligned.
Anti-periplanar geometry will put a bonding orbital and an anti-bonding orbital approximately parallel to each other, or syn-periplanar. Figure 6 is another representation of 2-chloro-2,3-dimethylbutane (Figure 5), showing the C–H bonding orbital, σ C–H, and the C–Cl anti-bonding orbital, σ* C–Cl, syn-periplanar.
The concepts of syn and anti addition are used to characterize the different reactions of organic chemistry by reflecting the stereochemistry of the products in a reaction. The type of addition that occurs depends on multiple different factors of a reaction, and is defined by the final orientation of the substituents on the parent molecule .
anti-edge Synonym for non-edge, a pair of non-adjacent vertices. anti-triangle A three-vertex independent set, the complement of a triangle. apex 1. An apex graph is a graph in which one vertex can be removed, leaving a planar subgraph. The removed vertex is called the apex. A k-apex graph is a graph that can be made planar by the removal of k ...
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The prefix endo is reserved for the isomer with the substituent located closest, or "syn", to the longest bridge. The prefix exo is reserved for the isomer with the substituent located farthest, or "anti", to the longest bridge. Here "longest" and "shortest" refer to the number of atoms that comprise the bridge.
A FBI document obtained by Wikileaks details the symbols and logos used by pedophiles to identify sexual preferences. According to the document members of pedophilic organizations use of ...