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The isotope selenium-75 has radiopharmaceutical uses. For example, it is used in high-dose-rate endorectal brachytherapy, as an alternative to iridium-192. [8]In paleobiogeochemistry, the ratio in amount of selenium-82 to selenium-76 (i.e, the value of δ 82/76 Se) can be used to track down the redox conditions on Earth during the Neoproterozoic era in order to gain a deeper understanding of ...
Selones (R 2 C=Se) are the selenium analogues of ketones. They are rare due to their tendency to oligomerize. [11] Diselenobenzoquinone is stable as a metal complex. [12] Selenourea is an example of a stable compound containing a C=Se bond. Thioselenides (R−Se−S−R), compounds with selenium(II)–sulfur(II) bonds, analogous to disulfides.
Selenium was originally developed by Jason Huggins in 2004 as an internal tool at ThoughtWorks. [5] Huggins was later joined by other programmers and testers at ThoughtWorks, before Paul Hammant joined the team and steered the development of the second mode of operation that would later become "Selenium Remote Control" (RC).
For example, selenomethionine and selenocysteine are selenium-containing amino acids present in the human body. Selenomethionine participates in the synthesis of selenoproteins . [ 2 ] The reduction potential and pKa (5.47) of selenocysteine are lower than those of cysteine , making some proteins have antioxidant activity. [ 3 ]
Selenium is found in metal sulfide ores, where it substitutes for sulfur. Commercially, selenium is produced as a byproduct in the refining of these ores. Minerals that are pure selenide or selenate compounds are rare. The chief commercial uses for selenium today are glassmaking and pigments. Selenium is a semiconductor and is used in photocells.
In the selenium cycle it has been found that bacteria, fungi, and plants, especially species of Astragalus, metabolize the most oxidized forms of selenium, selenate or selenite, to selenide. It is also thought that microorganisms may be able to oxidize selenium of valence zero to selenium of valence +6.
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The element selenium exhibits several valence states. Selenate is the least reduced, followed by selenite, and elemental selenium; selenide is even more reduced than elemental selenium. [6] The valence state is an important factor to the toxicity of selenium. Selenate is the form required by organisms that need selenium as a micronutrient.