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Manganese(VII) oxide (manganese heptoxide) is an inorganic compound with the formula Mn 2 O 7 Manganese heptoxide is a volatile liquid with an oily consistency. It is a highly reactive and powerful oxidizer that reacts explosively with nearly any organic compound.
It may refer more specifically to the following manganese minerals: Birnessite, (Na,Ca) 0.5 (Mn IV,Mn III) 2 O 4 · 1.5 H 2 O; Buserite, MnO 2 ·nH 2 O; Hausmannite, Mn II Mn III 2 O 4; Manganite, Mn III O(OH)
Gas exchange is the physical process by which gases move passively by diffusion across a surface. For example, this surface might be the air/water interface of a water body, the surface of a gas bubble in a liquid, a gas-permeable membrane, or a biological membrane that forms the boundary between an organism and its extracellular environment.
Mn 3 O 4 has the spinel structure, where the oxide ions are cubic close packed and the Mn II occupy tetrahedral sites and the Mn III octahedral sites. [3] The structure is distorted due to the Jahn–Teller effect. [3]
α-Mn 2 O 3 has the cubic bixbyite structure, which is an example of a C-type rare earth sesquioxide (Pearson symbol cI80, space group Ia 3, #206). The bixbyite structure has been found to be stabilised by the presence of small amounts of Fe 3+ , pure Mn 2 O 3 has an orthorhombic structure ( Pearson symbol oP24, space group Pbca, #61).
Exchange interaction is the main physical effect responsible for ferromagnetism, and has no classical analogue. For bosons, the exchange symmetry makes them bunch together, and the exchange interaction takes the form of an effective attraction that causes identical particles to be found closer together, as in Bose–Einstein condensation.
MnO has the distinction of being one of the first compounds [4] to have its magnetic structure determined by neutron diffraction, the report appearing in 1951. [5] This study showed that the Mn 2+ ions form a face centered cubic magnetic sub-lattice where there are ferromagnetically coupled sheets that are anti-parallel with adjacent sheets.
As an example, self-exchange describes the degenerate reaction between permanganate and its one-electron reduced relative manganate: [MnO 4 ] − + [Mn*O 4 ] 2− → [MnO 4 ] 2− + [Mn*O 4 ] − In general, if electron transfer is faster than ligand substitution, the reaction will follow the outer-sphere electron transfer route.