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The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
2 FeCl 3 + Fe → 3 FeCl 2. A traditional synthesis of anhydrous ferrous chloride is the reduction of FeCl 3 with chlorobenzene: [25] 2 FeCl 3 + C 6 H 5 Cl → 2 FeCl 2 + C 6 H 4 Cl 2 + HCl. iron(III) chloride releases chlorine gas when heated above 160 °C, generating ferrous chloride: [16] 2FeCl 3 → 2FeCl 2 + Cl 2
Potassium ferrioxalate contains the iron(III) complex [Fe(C 2 O 4) 3] 3−. In chemistry, iron(III) or ferric refers to the element iron in its +3 oxidation state. Ferric chloride is an alternative name for iron(III) chloride (FeCl 3). The adjective ferrous is used instead for iron(II) salts, containing the cation Fe 2+.
Substance Formula 0 °C 10 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Barium acetate: Ba(C 2 H 3 O 2) 2: 58.8: 62: 72: 75: 78.5: 77: 75
An alternative synthesis of anhydrous ferrous chloride is the reduction of FeCl 3 with chlorobenzene: [5] 2 FeCl 3 + C 6 H 5 Cl → 2 FeCl 2 + C 6 H 4 Cl 2 + HCl. For the preparation of ferrocene ferrous chloride is generated in situ by comproportionation of FeCl 3 with iron powder in tetrahydrofuran (THF). [6]
When Fe 2 O 3 ·H 2 O is heated, it loses its water of hydration. Further heating at 1670 K converts Fe 2 O 3 to black Fe 3 O 4 (Fe II Fe III 2 O 4), which is known as the mineral magnetite. Fe(O)OH is soluble in acids, giving [Fe(H 2 O) 6] 3+. In concentrated aqueous alkali, Fe 2 O 3 gives [Fe(OH) 6] 3−. [12]
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3 + 3 NaOH → Fe(OH) 3 + 3 NaNO 3. In fact, when dissolved in water, pure FeCl 3 will hydrolyze to some extent, yielding the oxyhydroxide and making the solution acidic: [11] FeCl 3 + 2 H 2 O ↔ FeOOH + 3 HCl. Therefore, the compound can also be obtained by the decomposition of acidic solutions of iron(III) chloride held near the boiling ...