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Other studies have similarly found minor but non-negligible energetic contributions from expanded octet structures in SF 6 (17%) and XeF 6 (14%). [ 8 ] Despite the lack of chemical realism, the IUPAC recommends the drawing of expanded octet structures for functional groups like sulfones and phosphoranes , in order to avoid the drawing of a ...
The bonding in carbon dioxide (CO 2): all atoms are surrounded by 8 electrons, fulfilling the octet rule. The octet rule is a chemical rule of thumb that reflects the theory that main-group elements tend to bond in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a noble gas.
In some general chemistry textbooks, hybridization is presented for main group coordination number 5 and above using an "expanded octet" scheme with d-orbitals first proposed by Pauling. However, such a scheme is now considered to be incorrect in light of computational chemistry calculations.
conclusion: with an octet electron count (on sulfur), we can anticipate that H 2 S would be pseudo-tetrahedral if one considers the two lone pairs. SCl 2, for the central S; neutral counting: S contributes 6 electrons, each chlorine radical contributes one each: 6 + 2 × 1 = 8 valence electrons
Valence Bond theory describes chemical bonding better than Lewis Theory, which states that atoms share or transfer electrons so that they achieve the octet rule. It does not take into account orbital interactions or bond angles, and treats all covalent bonds equally. [ 8 ]
A more accurate, but less commonly used name for 8 bits is octet. Commonly, a decimal SI metric prefix (such as kilo-) is used with bit and byte to express larger sizes (kilobit, kilobyte). But, this is usually inaccurate since these prefixes are decimal, whereas binary hardware size is usually binary.
A trick is to count up valence electrons, then count up the number of electrons needed to complete the octet rule (or with hydrogen just 2 electrons), then take the difference of these two numbers. The answer is the number of electrons that make up the bonds. The rest of the electrons just go to fill all the other atoms' octets.
[7] [8] While Lewis supported the viewpoint of expanded octet, invoking s-p-d hybridized orbitals and maintaining 2c–2e bonds between neighboring atoms, Langmuir instead opted for maintaining the octet rule, invoking an ionic basis for bonding in hypervalent compounds (see Hypervalent molecule, valence bond theory diagrams for PF 5 and SF 6). [9]